Reactive Distillation Modeling Using Artificial Neural Networks


Book Description

The use of artificial intelligence techniques in the design of processes has generated a line of research of interest, in areas of chemical engineering and especially in the so-called separation processes, in this chapter the combination of artificial neural networks (ANN) is presented and fuzzy dynamic artificial neural networks (DFANN). Applied to the calculation of thermodynamic properties and the design of reactive distillation columns, the ANN and DFANN are mathematical models that resemble the behavior of the human brain, the proposed models do not require linearization of thermodynamic equations, models of mass and energy transfer, this provides an approximate and tight solution compared to robust reactive distillation column design models. Generally, the models must be trained according to a dimensionless model, for the design of a reactive column a dimensionless model is not required, it is observed that the use of robust models for the design and calculation of thermodynamic properties give results that provide better results than those calculated with a commercial simulator such as Aspen Plus (R), it is worth mentioning that in this chapter only the application of neural network models is shown, not all the simulation and implementation are presented, mainly because it is a specialized area where not only requires a chapter for its explanation, it is shown that with a neural network of 16 inputs, 2 hidden layers and 16 outputs, it generates a robust calculation system compared to robust thermodynamic models that contain the same commercial simulator, a characteristic of the network presented is the minimization of overlearning in which the network by its very nature is low. In addition, it is shown that it is a dynamic model that presents adjustment as a function of time with an approximation of 96,Äì98% of adjustment for commercial simulator models such as Aspen Plus (R), the DFANN is a viable alternative for implementation in processes of separation, but one of the disadvantages of the implementation of these techniques is the experience of the programmer both in the area of artificial intelligence and in separation processes.




Artificial Neural Network (ANN) Modeling of Reactive Distillation


Book Description

As a result of good modeling capabilities, neural networks have been used extensively for a number of chemical engineering applications such as sensor data analysis, fault detection and nonlinear process identification. However, only in recent years, with the upsurge in the research on nonlinear control, its use in process control has been widespread. But there is almost no work which has tested the capacity of Artificial Neural Network (ANN) to model Reactive Distillation (RD). The superiority of ANN was tested for the synthesis of 2-methylpropylacetate from 2-methylpropanol and acetic acid by RD. The effects of various parameters like feed, temperature, reflux ratio, and boil-up ratio, each varied at three levels, were studied. At each combination, the composition of distillate and bottom was predicted by Aspen simulation. An appropriate ANN model was fitted using generated data. A three-layered feed-forward back-propagation model, with 3, 5 and 4 neurons in the layers, was fitted. Log-sig function was used in each layer. The model was found to have high R2 (= 0.993) value and good predicting capability.




Reactive Distillation


Book Description

Neural Networks is an integral part in machine learning and a known tool for controlling nonlinear processes. The area is under rapid development and provides a tool for modelling and controlling of advanced processes. This book provides a comprehensive overview for modelling, simulation, measurement and control strategies for reactive distillations using neural networks.




Reactive Distillation Design and Control


Book Description

After an overview of the fundamentals, limitations, and scope of reactive distillation, this book uses rigorous models for steady-state design and dynamic analysis of different types of reactive distillation columns and quantitatively compares the economics of reactive distillation columns with conventional multi-unit processes. It goes beyond traditional steady-state design that primarily considers the capital investment and energy costs when analyzing the control structure and the dynamic robustness of disturbances, and discusses how to maximize the economic and environmental benefits of reactive distillation technology.







Reactive Distillation


Book Description

In a reactive distillation column, both the chemical conversion and the distillative separation of the product mixture are carried out simultaneously. Through this integrative strategy, chemical equilibrium limitations can be overcome, higher selectivities can be achieved and heat of reaction can be directly used for distillation. Increased process efficiency and reduction of investments and operational costs are the direct results of this approach. Highly renowned international experts from both industry and academia review the state-of-the-art and the future directions in application, design, analysis and control of Reactive Distillation processes. Part I surveys various industrial applications and covers both established large scale processes as well as new chemical reaction schemes with high future potential. Part II provides the vital details for analysis of reactive phase equilibria, and discusses the importance of chemical reaction kinetics, while Part III focuses on identifying feasible column configurations and designing their internal structure. Analysis and control of the complex dynamic and steady-state behavior of reactive distillation processes are described in Part IV. Reactive Distillation - a very promising alternative to conventional reaction-distillation flow schemes.




Distillation


Book Description

The purpose of this book is to offer readers important topics on the modeling, simulation, and optimization of distillation processes. The book is divided into four main sections: the first section is introduction to the topic, the second presents work related to distillation process modeling, the third deals with the modeling of phase equilibrium, one of the most important steps of distillation process modeling, and the the fourth looks at the reactive distillation process, a process that has been applied successfully to a number of applications and has been revealed as a promising strategy for a number of recent challenges.




23 European Symposium on Computer Aided Process Engineering


Book Description

Reactive Distillation (RD) which combines reaction and distillation can be advantageously used to obtain desired selectivities in case of multi-reaction system. In case of azeotropic systems, the presence of complex vapor liquid equilibrium and distillation boundaries, shrink the feasible stage composition region and thereby increase design complexity for RD systems. Therefore an attempt is made here to develop a conceptual design algorithm based on boundary value method for the synthesis of single feed hybrid reactive distillation (HRD) column to obtain desired selectivities in case of single reactant complex reaction scheme (vande Vusse reaction) involving azeotropic systems. This work is the continuation of our earlier work on ideal multicomponent system (). We believe that the conceptual design algorithm developed here can be extended to more complex schemes involving multiple reactants.




Distillation Processes


Book Description

Distillation is an important separation technique that has been used for many centuries to exploit the volatility differences between components in a mixture. The distillation process has many variations and applications. This book includes two sections on desalination and reactive distillation. It discusses desalination in the processes of solar and membrane distillation, with a focus on the reduction of energy costs to obtain potable water. It also discusses reactive distillation, which can be used in some cases to reduce the power duty in the separation process by using the reaction heat directly in the separation. The book includes cases of mathematical modeling, simulation, and optimization of the distillation process.




Distillation


Book Description

The purpose of this book is to offer innovative applications of the distillation process. The book is divided in two main sections, one containing chapters that deal with process design and calculations, and the other, chapters that discuss distillation applications. Moreover, the chapters involve wide applications as in fruit spirits production, in organic liquid compounds produced by oil and fats cracking, energy evaluation in distillation processes, and applicability of solar membrane distillation. I believe that this book will provide new ideas and possibilities of the development of innovative research lines for the readers.