Thermal Oxidation Stability of Diesel Fuels


Book Description

Injector fouling bench tests(IFBT) and modified Jet Fuel Thermal Oxidation Test(JFTOT, ASTMD 3241) have been used to develop methodology for evaluating the thermal stability of diesel fuels. A new method for measuring the thickness of lacquer-type fuel deposits formed on test surfaces at elevated temperatures has been developed and applied to a variety of fuels, both with and without MIL-S-53021(additive stabilizer package). The utility of this technique greatly expands the capability for exploring and defining diesel fuel thermal stability with respect to both material and kinetic studies. Correlation of IFBT and JFTOT types tests including definitions of temperature, flow, test surface metallurgy and fuel additive effects can now be performed to better understand diesel thermal stability and provide test methodology/test limit information for fuel specification consideration.







Heat Transfer, Fluid Dynamics, and Autoxidation Studies in the Jet Fuel Thermal Oxidation Tester (JFTOT)


Book Description

Modern military aircraft use jet fuel as a coolant before it is burned in the combustor. Prior to combustion, dissolved O2 and other heteroatomic species react with the heated fuel to form insoluble particles and surface deposits that can impair engine performance. For safe aircraft operation, it is important to minimize jet fuel oxidation and resultant surface deposition in critical aircraft components. The Jet Fuel Thermal Oxidation Tester (JFTOT) is a thermal stability test that measures the tendency for fuel to form such deposits and delivers a pass/fail grade for each fuel tested. However, the extent of oxidation and the corresponding deposition occurring in the JFTOT is not fully understood. A JFTOT Model Mark II was modified to include a bulk outlet thermocouple measurement and a downstream oxygen sensor to measure bulk oxygen consumption. Experimental results show a direct relationship between the bulk outlet temperature and JFTOT setpoint temperature with the bulk outlet less than the setpoint temperature. Several fuels were also tested at varying setpoint temperatures with complete oxygen consumption by 320°C and a wide range of oxygen consumption from 10-85% at 260°C. Due to the complex fluid flows in the JFTOT, computational fluid dynamics (CFD) was used to model the heat transfer and fluid flow. A three-dimensional simulation showed considerable recirculation within the JFTOT due to buoyancy effects from gravity and resulted in complex residence time behavior. In addition, CFD simulations performed with a pseudo-detailed chemical kinematic mechanism showed an under prediction in both oxidation and deposition for similar fuels tested experimentally but yielded bulk outlet temperature predictions of less than 2% error. Simulations of deposition were of the right order of magnitude and matched the deposit profile of comparable experimental ellipsometry data.




Analysis of Jet Fuel Thermal Oxidation Deposits by Spectral Fluorometric Technique


Book Description

The Jet Fuel Thermal Oxidation Test (JFTOT) is a widely used ASTM test procedure that evaluates the thermal stability of a fuel. It is evidenced by the fuel's resistance to undergo any chemical changes during increased thermal oxidative stress, until such time that a thermal breakpoint temperature is reached. A characteristic trace of the fuel is then deposited onto an aluminum test coupon and the fuel is rated on a pass/fail books relative to industry standards. Current rating systems approved by the industry for evaluating these tube deposit formations often fail to generate repeatable rating results. The required visual inspection of these deposit areas produces considerable uncertainty among many reviewers (due to a host of uncontrolled variables within the human observer). This paper will focus on the needs of the industry for an improved method of evaluating jet fuel thermal oxidation deposits using laser-induced spectral flourometry (SF). A novel device for reading these tube deposit areas from the cylindrical surface of an aluminum test coupon will be described as well. The overall technique yields an array of objective criteria for the evaluation of heater tube deposit areas and shows great potential for the identification of individual jet fuels on the basis of their fluorescent profiles.







Effect of Test Pressure on Fuel Thermal Stability Test Methods


Book Description

The boiling of turbine fuels in contact with the metal surface of the Jet Fuel Thermal Oxidation Tester (JFTOT) test section was investigated. The boiling inception pressure was determined at several temperatures. Incipient boiling was determined by observing the pressure-temperature combination at which a power increase occurred in order to vaporize the fuel. A glass test housing was used to visually determine the bubble points of the fuels. The initiation of boiling was found to occur at the pressure-temperature combination where an increase in power was required to vaporize the fuel. Thus, the two techniques used produce identical results. The bubble points for various fuels were calculated using ASTM Method D-2889, Calculation of True Vapor Pressure of Petroleum Distillate Fuels. Good agreement exists between the measured bubble points and the calculated bubble points. Data is presented to show that boiling of the fuel may adversely affect the apparent thermal stability breakpoint of the fuel. It is recommended that the JFTOT operating pressure be increased from 400 psig to 500 psig to decrease the probability of fuel boiling in the JFTOT during a test. Based on lower operating pressure of the ASTM/CRC Fuel Coker, it is apparent that boiling of JP-4 and Jet B wide-cut fuels is likely under the current jet fuel test conditions of 300/400 F. Thus, the Fuel Coker thermal stability breakpoints of wide-cut fuels are likely to be in error. (Author).