Contaminants in the Subsurface


Book Description

At hundreds of thousands of commercial, industrial, and military sites across the country, subsurface materials including groundwater are contaminated with chemical waste. The last decade has seen growing interest in using aggressive source remediation technologies to remove contaminants from the subsurface, but there is limited understanding of (1) the effectiveness of these technologies and (2) the overall effect of mass removal on groundwater quality. This report reviews the suite of technologies available for source remediation and their ability to reach a variety of cleanup goals, from meeting regulatory standards for groundwater to reducing costs. The report proposes elements of a protocol for accomplishing source remediation that should enable project managers to decide whether and how to pursue source remediation at their sites.







Ecotoxicology of Explosives


Book Description

Managing sites contaminated with munitions constituents is an international challenge. Although the choice of approach and the use of Ecological Risk Assessment (ERA) tools may vary from country to country, the assurance of quality and the direction of ecotoxicological research are universally recognized as shared concerns. Drawing on a multidiscip




Transport & Fate of Chemicals in Soils


Book Description

During the last four decades, tremendous advances have been made towards the understanding of transport characteristics of contaminants in soils, solutes, and tracers in geological media. Transport & Fate of Chemicals in Soils: Principles & Applications offers a comprehensive treatment of the subject complete with supporting examples of mathematical models that describe contaminants reactivity and transport in soils and aquifers. This approach makes it a practical guide for designing experiments and collecting data that focus on characterizing retention as well as release kinetic reactions in soils and contaminant transport experiments in the laboratory, greenhouse), and in the field. The book provides the basic framework of the principals governing the sorption and transport of chemicalsin soils. It focuses on physical processes such as fractured media, multiregion, multiple porosities, and heterogeneity and effect of scale as well as chemical processes such as nonlinear kinetics, release and desorption hysteresis, multisite and multireaction reactions, and competitive-type reactions. The coverage also includes details of sorption behavior of chemicals with soil matrix surfaces as well the integration of sorption characteristics with mechanisms that govern solute transport in soils. The discussions of applications of the principles of sorption and transport are not restricted to contaminants, but also include nitrogen, phosphorus, and trace elements including essential micronutrients, heavy metals, military explosives, pesticides, and radionuclides. Written in a very clear and easy-to-follow language by a pioneer in soil science, this book details the basic framework of the physical and chemical processes governing the transport of contaminants, trace elements, and heavy metals in soils. Highly practical, it includes laboratory methods, examples, and empirical formulations. The approach taken by the author gives you not only the fundamentals of understanding of reactive chemicals retention and their transport in soils and aquifers, but practical guidance you can put to immediate use in designing experiments and collecting data.




Energetic Materials and Munitions


Book Description

Provides a hands-on approach to demilitarization and environmental aspects of energetic materials and munitions This book gives an overview of the environmental impact of the production, use, and cleanup of energetic materials and munitions. It provides scientists, engineers, environmental specialists, and users with the understanding of environmental issues for munitions and of the ways to improve design and manage potential risks. It covers the various aspects of how chemical properties influence fate, transport, and toxicity of new formulations and prescribes tools for reducing or alleviating environmental risks. In addition, it discusses pyrotechnics and the problem of dealing with munitions underwater. Chapters in Energetic Materials and Munitions: Life Cycle Management, Environmental Impact and Demilitarization look at demilitarization in general, as well as in the future. Topics covered include logistics, costs, and management; life cycle analysis and management; and greener munitions. Another introduces readers to the "One Health" approach in the design of sustainable munition compounds. Following that, readers are taught about land assessment for munitions-related contamination in military live-fire training. The book also examines the development and integration of environmental, safety, and occupational health information. -Brings together in one source expertise and in-depth information on the current and future state of how we handle the production, use, and demilitarization of explosives and weaponry -A handy reference for experienced practitioners, as well as for training young professionals in the field -Every chapter contains real-life examples and proposes future directions for the field Energetic Materials and Munitions: Life Cycle Management, Environmental Impact and Demilitarization is an important book for explosives specialists, pyrotechnicians, materials scientists, military authorities, safety officers, health officers, and chemical engineers.




Bioremediation of Energetics, Phenolics, and Polycyclic Aromatic Hydrocarbons


Book Description

The symposium included 600 presentations in 50 sessions on bioremediation and supporting technologies used for a wide range of contaminants already in, or poised to invade, soil, groundwater, and sediment. Three hundred and fifty-two papers were selected and organized into ten volumes. Volume three presents bench- and pilot- scale projects focusing on the use of biological treatment approaches for remediating problem compounds such as RDX, HMX, TNT, DDT, PCBs, PAHs, and chlorophenols. Articles average eight pages, and contain abstracts and references. Annotation copyrighted by Book News Inc., Portland, OR.




Energetic Materials


Book Description

This volume provides an overview of current research and recent advances in the area of energetic materials, focusing on decomposition, crystal and molecular properties. The contents and format reflect the fact that theory, experiment and computation are closely linked in this field. Since chemical decomposition is of fundamental importance in energetic performance, this volume begins with a survey of the decomposition processes of a variety of energetic compounds. This is followed by detailed studies of certain compounds and specific mechanisms, such as nitro/aci-nitro tautomerism. Chapter 6 covers the transition from decomposition to crystal properties, with molecular dynamics being the primary analytical tool. The next several chapters deal with different aspects of the crystalline state, again moving from the general to particular. There is also a discussion of methods for computing gas, liquid and solid phase heats of formation. Finally, the last portion of this volume looks at the potential of high-nitrogen molecules as energetic systems; this has been of considerable interest in recent years.Overall, this volume illustrates the progress that has been made in the field of energetic materials and some of the areas of current activity. It also indicates the challenges involved in characterizing and understanding the properties and behaviour of these compounds. The work is a unique state-of-the-art treatment of the subject, written by pre-eminent researchers in the field.- Overall emphasis is on theory and computation, presented in the context of relevant experimental work- Presents a unique state-of-the-art treatment of the subject- Contributors are preeminent researchers in the field




Reviews of Environmental Contamination and Toxicology


Book Description

Reviews of Environmental Contamination and Toxicology provides detailed review articles concerned with aspects of chemical contaminants, including pesticides, in the total environment with toxicological considerations and consequences.