Author : Alan J. Heeger
Publisher : OUP Oxford
Page : 288 pages
File Size : 16,59 MB
Release : 2010-07-29
Category : Science
ISBN : 0198528647
The unique properties of conducting and semiconducting (conjugated) polymers make them one of the most attractive areas of interdisciplinary materials science and technology. Written by a pioneer in the field, this book is the first aimed at teaching graduate students, postdoctoral scientists, and specialists in industry about this exciting field.
Author : Helmut Kiess
Publisher : Springer Science & Business Media
Page : 320 pages
File Size : 36,13 MB
Release : 2012-12-06
Category : Science
ISBN : 3642467296
This book reviews the current understanding of electronic, optical and magnetic properties of conjugated polymers in both the semiconducting and metallic states. It introduces in particular novel phenomena and concepts in these quasi one-dimensional materials that differ from the well-established concepts valid for crystalline semiconductors. After a brief introductory chapter, the second chapter presents basic theore tical concepts and treats in detail the various models for n-conjugated polymers and the computational methods required to derive observable quantities. Specific spatially localized structures, often referred to as solitons, polarons and bipolarons, result naturally from the interaction between n-electrons and lattice displacements. For a semi-quantitative understanding of the various measure ments, electron-electron interactions have to be incorporated in the models; this in turn makes the calculations rather complicated. The third chapter is devoted to the electrical properties of these materials. The high metallic conductivity achieved by doping gave rise to the expression conducting polymers, which is often used for such materials even when they are in their semiconducting or insulating state. Although conductivity is one of the most important features, the reader will learn how difficult it is to draw definite conclusions about the nature of the charge carriers and the microscopic transport mechanism solely from electrical measurements. Optical properties are discussed in the fourth chapter.
Author : Pradip Kar
Publisher : John Wiley & Sons
Page : 176 pages
File Size : 25,36 MB
Release : 2013-08-26
Category : Technology & Engineering
ISBN : 1118573803
An A-to-Z of doping including its definition, its importance, methods of measurement, advantages and disadvantages, properties and characteristics—and role in conjugated polymers The versatility of polymer materials is expanding because of the introduction of electro-active behavior into the characteristics of some of them. The most exciting development in this area is related to the discovery of intrinsically conductive polymers or conjugated polymers, which include such examples as polyacetylene, polyaniline, polypyrrole, and polythiophene as well as their derivatives. "Synmet" or "synthetic metal" conjugated polymers, with their metallic characteristics, including conductivity, are of special interest to researchers. An area of limitless potential and application, conjugated polymers have sparked enormous interest, beginning in 2000 when the Nobel Prize for the discovery and development of electrically conducting conjugated polymers was awarded to three scientists: Alan J. Heeger, Alan G. MacDiarmid, and Hideki Shirakawa. Conjugated polymers have a combination of properties—both metallic (conductivity) and polymeric; doping gives the conjugated polymer's semiconducting a wide range of conductivity, from insulating to low conducting. The doping process is a tested effective method for producing conducting polymers as semiconducting material, providing a substitute for inorganic semiconductors. Doping in Conjugated Polymers is the first book dedicated to the subject and offers a comprehensive A-to-Z overview. It details doping interaction, dopant types, doping techniques, and the influence of the dopant on applications. It explains how the performance of doped conjugated polymers is greatly influenced by the nature of the dopants and their level of distribution within the polymer, and shows how the electrochemical, mechanical, and optical properties of the doped conjugated polymers can be tailored by controlling the size and mobility of the dopants counter ions. The book also examines doping at the nanoscale, in particular, with carbon nanotubes. Readership The book will interest a broad range of researchers including chemists, electrochemists, biochemists, experimental and theoretical physicists, electronic and electrical engineers, polymer and materials scientists. It can also be used in both graduate and upper-level undergraduate courses on conjugated polymers and polymer technology.
Author : Georges Hadziioannou
Publisher : John Wiley & Sons
Page : 786 pages
File Size : 13,48 MB
Release : 2006-12-15
Category : Technology & Engineering
ISBN : 3527312714
Halbleitende Polymere sind ein faszinierendes interdisziplinäres Forschungsgebiet, das kurz vor dem anwendungstechnischen Durchbruch steht. Insbesondere für neue Komponenten in der Photonik und Optoelektronik bieten diese Materialien ein enormes Potential. Dieses zweibändige Handbuch mit Beiträgen herausragender Experten aus den Feldern Organische und Physikalische Chemie, Festkörperphysik bis hin zur Verfahrenstechnik, beschreibt detailliert die Grundlagen, die zum Verständnis und zur Kontrolle dieser faszinierenden Materialien notwendig sind.
Author : Christine Luscombe
Publisher : Royal Society of Chemistry
Page : 293 pages
File Size : 38,56 MB
Release : 2016-10-12
Category : Technology & Engineering
ISBN : 1782624007
Semiconducting polymers are of great interest for applications in electroluminescent devices, solar cells, batteries and diodes. In recent years vast advances have been made in the area of controlled synthesis of semiconducting polymers, specifically polythiophenes. The book is separated into two main sections, the first will introduce the advances made in polymer synthesis, and the second will focus on the microstructure and property analysis that has been enabled because of the recent advances in synthetic strategies. Edited by one of the leaders in the area of polythiophene synthesis, this new book will bring the field up to date with more recent models for understanding semiconducting polymers. The book will be applicable to materials and polymers chemists in industry and academia from postgraduate level upwards.
Author : György Inzelt
Publisher : Springer Science & Business Media
Page : 282 pages
File Size : 42,77 MB
Release : 2008-04-08
Category : Science
ISBN : 3540759301
This book is a systematic survey of the knowledge accumulated in this field in the last thirty years. It includes material on the thermodynamic aspects of the polymers, the theory of the mechanism of charge transport processes, and the chemical and physical properties of these compounds. Also covered are the techniques of characterization, the electrochemical methods of synthesis, and the application of these systems. Inzelt’s book is a must-read for electrochemists and others.
Author : S.K. Bhattacharya
Publisher : CRC Press
Page : 378 pages
File Size : 39,79 MB
Release : 1986-09-10
Category : Technology & Engineering
ISBN : 9780824775551
Discussing every aspect of the fabrication, properties, and use of metal-filled polymers, this unique single-source reference covers the full range of current and potential applications -- from the insulation to the conduction level. Metal-Filled Polymers describes the most recent experimentation in determining the shielding effectiveness of plastics filled with metal ... compares the advantages of metal fillers over conventional nonmetallic fillers ... delineates the concept of interphase (which has recently found importance in predicting the mechanism of crack growth) ... and shows how the geometry and orientation of filler particles affect conduction, strength, and stiffness under various loading conditions. In addition, the book explains how the filler interacts with the matrix to improve composite properties ... and details the theoretical development of both mechanical and thermal properties. Encompassing the entire literature on their respective topics, contributions by eminent researchers focus on the very latest state-of-the-art data and relate findings directly to practical uses in current technology. Metal-Filled Polymers will prove a vital reference for plastics, materials, process, chemical, design, and mechanical engineers and managers in the plastics and metals industries. It will also be a useful resource for manufacturers of conductive composites for EMI shielding, and professional seminars and graduate-level courses in composite materials. Book jacket.
Author : David Levy
Publisher : John Wiley & Sons
Page : 390 pages
File Size : 21,44 MB
Release : 2019-04-29
Category : Technology & Engineering
ISBN : 3527342079
Edited by well-known pioneers in the field, this handbook and ready reference provides a comprehensive overview of transparent conductive materials with a strong application focus. Following an introduction to the materials and recent developments, subsequent chapters discuss the synthesis and characterization as well as the deposition techniques that are commonly used for energy harvesting and light emitting applications. Finally, the book concludes with a look at future technological advances. All-encompassing and up-to-date, this interdisciplinary text runs the gamut from chemistry and materials science to engineering, from academia to industry, and from fundamental challenges to readily available applications.
Author : Masayoshi Higuchi
Publisher : Springer Nature
Page : 92 pages
File Size : 28,53 MB
Release : 2019-11-12
Category : Technology & Engineering
ISBN : 4431568913
This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
Author : Oksana Ostroverkhova
Publisher : Woodhead Publishing
Page : 914 pages
File Size : 19,44 MB
Release : 2018-11-30
Category : Technology & Engineering
ISBN : 0081022859
Handbook of Organic Materials for Electronic and Photonic Devices, Second Edition, provides an overview of the materials, mechanisms, characterization techniques, structure-property relationships, and most promising applications of organic materials. This new release includes new content on emerging organic materials, expanded content on the basic physics behind electronic properties, and new chapters on organic photonics. As advances in organic materials design, fabrication, and processing that enabled charge unprecedented carrier mobilities and power conversion efficiencies have made dramatic advances since the first edition, this latest release presents a necessary understanding of the underlying physics that enabled novel material design and improved organic device design. - Provides a comprehensive overview of the materials, mechanisms, characterization techniques, and structure property relationships of organic electronic and photonic materials - Reviews key applications, including organic solar cells, light-emitting diodes electrochemical cells, sensors, transistors, bioelectronics, and memory devices - New content to reflect latest advances in our understanding of underlying physics to enable material design and device fabrication
