Introduction to Solid State Ionics


Book Description

Introduction to Solid State Ionics: Phenomenology and Applications presents a pedagogical, graduate-level treatment of the science and technology of superionic conductors, also known as fast ion conductors or solid electrolytes. Suitable for physics, materials science, and engineering researchers and students, the text emphasizes basic physics and




Solid State Ionics for Batteries


Book Description

In this book, recent progress in batteries is firstly reviewed by researchers in three leading Japanese battery companies, SONY, Matsushita and Sanyo, and then the future problems in battery development are stated. Then, recent development of solid state ionics for batteries, including lithium ion battery, metal-hydride battery, and fuel cells, are reviewed. A battery comprises essentially three components: positive electrode, negative electrode, and electrolyte. Each component is discussed for the construction of all-solid-state Batteries. Theoretical understanding of properties of battery materials by using molecular orbital calculations is also introduced.




Solid State Batteries: Materials Design and Optimization


Book Description

The field of solid state ionics is multidisciplinary in nature. Chemists, physicists, electrochimists, and engineers all are involved in the research and development of materials, techniques, and theoretical approaches. This science is one of the great triumphs of the second part of the 20th century. For nearly a century, development of materials for solid-state ionic technology has been restricted. During the last two decades there have been remarkable advances: more materials were discovered, modem technologies were used for characterization and optimization of ionic conduction in solids, trial and error approaches were deserted for defined predictions. During the same period fundamental theories for ion conduction in solids appeared. The large explosion of solid-state ionic material science may be considered to be due to two other influences. The first aspect is related to economy and connected with energy production, storage, and utilization. There are basic problems in industrialized countries from the economical, environmental, political, and technological points of view. The possibility of storing a large amount of utilizable energy in a comparatively small volume would make a number of non-conventional intermittent energy sources of practical convenience and cost. The second aspect is related to huge increase in international relationships between researchers and exchanges of results make considerable progress between scientists; one find many institutes joined in common search programs such as the material science networks organized by EEC in the European countries.




Solid State Ionics


Book Description

Researchers in the new interdisciplinary field of solid state ionics will find this book indispensable because * it is one of the first volumes to consider the whole concept of solid state ionics, ranging from the research of solid electrolytes to the investigation and modelling of mixed conductors * it covers the fundamentals, materials and applications of solid state ionics * it presents mixed conduction and related materials in separate chapters * it offers a carefully thought out balance between traditional achievements and recent developments. Specialists and newcomers will appreciate the emphasis on applications and will find the book a handy reference work and fertile source of ideas for future research.




Physical Chemistry of Ionic Materials


Book Description

Defects play an important role in determining the properties of solids. This book provides an introduction to chemical bond, phonons, and thermodynamics; treatment of point defect formation and reaction, equilibria, mechanisms, and kinetics; kinetics chapters on solid state processes; and electrochemical techniques and applications. * Offers a coherent description of fundamental defect chemistry and the most common applications. * Up-to-date trends and developments within this field. * Combines electrochemical concepts with aspects of semiconductor physics.




Fast Ion Transport in Solids


Book Description

The main motivation for the organization of the Advanced Research Workshop in Belgirate was the promotion of discussions on the most recent issues and the future perspectives in the field of Solid State lonics. The location was chosen on purpose since Belgirate was the place were twenty years ago, also then under the sponsorship of NATO, the very first international meeting on this important and interdisciplinary field took place. That meeting was named "Fast Ion Transport in Solids" and gathered virtually everybody at that time having been active in any aspect of motion of ions in solids. The original Belgirate Meeting made for the first time visible the technological potential related to the phenomenon of the fast ionic transport in solids and, accordingly, the field was given the name "Solid State lonics". This field is now expanded to cover a wide range of technologies which includes chemical sensors for environmental and process control, electrochromic windows, mirrors and displays, fuel cells, high performance rechargeable batteries for stationary applications and electrotraction, chemotronics, semiconductor ionics, water electrolysis cells for hydrogen economy and other applications. The main idea for holding an anniversary meeting was that of discussing the most recent issues and the future perspectives of Solid State lonics just twenty years after it has started at the same location on the lake Maggiore in North Italy.




Solid State Electrochemistry


Book Description

This book describes, for the first time in a modern text, the fundamental principles on which solid state electrochemistry is based. In this sense it is in contrast to other books in the field which concentrate on a description of materials. Topics include solid (ceramic) electrolytes, glasses, polymer electrolytes, intercalation electrodes, interfaces and applications. The different nature of ionic conductivity in ceramic, glassy and polymer electrolytes is described as are the thermodynamics and kinetics of intercalation reactions. The interface between solid electrolytes and electrodes is discussed and contrasted with the more conventional liquid state electrochemistry. The text provides an essential foundation of understanding for postgraduates or others entering the field for the first time and will also be of value in advanced undergraduate courses.




Diffusion in Solids


Book Description

Diffusion in Solids: Recent Developments provides an overview of diffusion in crystalline solids. This book discusses the various aspects of the theory of diffusion. Organized into nine chapters, this volume starts with a discussion on the process of diffusion in solids. This book then examines the tools that supplement the conventional diffusion measurements, including electromigration, ionic conductivity, isotope effects, and vacancy wind effects. This text explores the molecular dynamic calculation by which the interatomic forces must be assumed. Other chapters discuss the method of measurement of the isotope effect on diffusion, which is the most powerful method of determining relevant information about the correlation factor. This volume extensively discusses diffusion in organic and amorphous materials, as well as interstitial diffusion in solids. The final chapter deals with ionic motion and diffusion in various groups of materials called fast ionic conductors. Solid-state physicists, materials scientists, physical chemists, and electrochemists will find this book extremely useful.




Solid Electrolytes and Their Applications


Book Description

Defect solid state has been an area of major scientific and technological interest for the last few decades, the resulting important applications sus taining this interest. Solid electrolytes represent one area of defect solid state. The early work on defect ionic crystals and, in particular, the classic results of Kiukkola and Wagner in 1957 on stabilized zirconia and doped thoria laid the foundation for a systematic study of solid electrolytes. In the same year, Ure reported on the ionic conductivity of calcium fluoride. Since then, intense worldwide research has advanced our understanding of the defect structure and electrical conductivity of oxygen ion conductors such as doped zirconia and thoria and of the fluorides. This paved the way for thermo dynamic and kinetic studies using these materials and for technological applications based on the oxygen ion conductors. In the last few years we have seen the emergence of two new classes of solid electrolytes of great signifi cance: the fJ-aluminas and the silver ion conductors. The significance of these discoveries is that now (i) solid electrolytes are available which at room temperature exhibit electrical conductivity comparable to that of liquid electrolytes, (ii) useful electrical conductivity values can be achieved over a wide range of temperature and ambient conditions, and (iii) a wide variety of ions are available as conducting species in solids. The stage is therefore set for a massive effort at developing applications.




Advanced Batteries


Book Description

Storage and conversion are critical components of important energy-related technologies. "Advanced Batteries: Materials Science Aspects" employs materials science concepts and tools to describe the critical features that control the behavior of advanced electrochemical storage systems. This volume focuses on the basic phenomena that determine the properties of the components, i.e. electrodes and electrolytes, of advanced systems, as well as experimental methods used to study their critical parameters. This unique materials science approach utilizes concepts and methodologies different from those typical in electrochemical texts, offering a fresh, fundamental and tutorial perspective of advanced battery systems. Graduate students, scientists and engineers interested in electrochemical energy storage and conversion will find "Advanced Batteries: Materials Science Aspects" a valuable reference.