Some Studies of Thermal and Photochemical Gas Phase Reactions
Author : P. J. Baldwin
Publisher :
Page : pages
File Size : 13,21 MB
Release : 1985
Category :
ISBN :
Author : P. J. Baldwin
Publisher :
Page : pages
File Size : 13,21 MB
Release : 1985
Category :
ISBN :
Author : V.N. Kondratiev
Publisher : Springer Science & Business Media
Page : 254 pages
File Size : 16,63 MB
Release : 2012-12-06
Category : Science
ISBN : 3642676081
The present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.
Author : Richard Graham Hopkins
Publisher :
Page : pages
File Size : 17,77 MB
Release : 1971
Category :
ISBN :
Author : Guy-Marie Come
Publisher :
Page : 356 pages
File Size : 22,59 MB
Release : 2014-01-15
Category :
ISBN : 9789401598064
Author : Robert Charles Stephen Grant
Publisher :
Page : pages
File Size : 42,63 MB
Release : 1966
Category : Gases
ISBN :
Author : Keiji Morokuma
Publisher :
Page : 18 pages
File Size : 14,11 MB
Release : 1998
Category :
ISBN :
Understanding the mechanism, kinetics and dynamics of elementary gas phase reactions is one of the major goals of chemistry. Such understanding is also essential to predicting and understanding plasma dynamics and optical radiation associated with the spacecraft-atmosphere interactions. The objective of the present research was to provide, based on mainly the ab initio molecular orbital and some dynamics calculations, theoretical information concerning the potential energy surfaces that dictate the kinetics and dynamics of gas phase elementary reactions. The reactions studied include ion-molecule reactions, photochemical reactions and neutral elementary reactions. Many of the systems for which theoretical calculations were performed in the present research are relevant to atmospheric chemistry and chemical lasers. Many systems were chosen based on the experimental studies and in collaboration with scientists at Air Force Research Laboratory, in order to provide them with some new insight that is not easily available without theoretical studies.
Author :
Publisher : Elsevier
Page : 281 pages
File Size : 34,77 MB
Release : 1996-05-14
Category : Science
ISBN : 0080550886
Advances in Gas Phase Ion Chemistry
Author : Yannick Vallee
Publisher : CRC Press
Page : 322 pages
File Size : 50,23 MB
Release : 1998-01-29
Category : Science
ISBN : 9789056990817
Flash Vacuum Thermolysis (FVT) techniques have become well-established methods and occupy an increasingly important place in synthesis. Gas Phase Reactions in Organic Synthesis is a complete review of the applications of flash vacuum thermolysis in organic chemistry; it features new developments in FVT, flow thermolysis and vacuum gas-solid reactions which have appeared in scientific literature since 1980.
Author : Barbara J. Finlayson-Pitts
Publisher : Elsevier
Page : 993 pages
File Size : 14,66 MB
Release : 1999-11-17
Category : Science
ISBN : 0080529070
Here is the most comprehensive and up-to-date treatment of one of the hottest areas of chemical research. The treatment of fundamental kinetics and photochemistry will be highly useful to chemistry students and their instructors at the graduate level, as well as postdoctoral fellows entering this new, exciting, and well-funded field with a Ph.D. in a related discipline (e.g., analytical, organic, or physical chemistry, chemical physics, etc.). Chemistry of the Upper and Lower Atmosphere provides postgraduate researchers and teachers with a uniquely detailed, comprehensive, and authoritative resource. The text bridges the "gap" between the fundamental chemistry of the earth's atmosphere and "real world" examples of its application to the development of sound scientific risk assessments and associated risk management control strategies for both tropospheric and stratospheric pollutants. - Serves as a graduate textbook and "must have" reference for all atmospheric scientists - Provides more than 5000 references to the literature through the end of 1998 - Presents tables of new actinic flux data for the troposphere and stratospher (0-40km) - Summarizes kinetic and photochemical date for the troposphere and stratosphere - Features problems at the end of most chapters to enhance the book's use in teaching - Includes applications of the OZIPR box model with comprehensive chemistry for student use
Author : T. M. Sugden
Publisher : Cambridge University Press
Page : 412 pages
File Size : 33,69 MB
Release : 2010-06-24
Category : Science
ISBN : 9780521147477
This book examines very simple atomic reactions to more complex chain reactions involving combustion, flame and the production of polymers.