Supramolecular Chemistry


Book Description

Supramolecular chemistry is ‘chemistry beyond the molecule’ - the chemistry of molecular assemblies and intermolecular bonds. It is one of today’s fastest growing disciplines, crossing a range of subjects from biological chemistry to materials science; and from synthesis to spectroscopy. Supramolecular Chemistry is an up-to-date, integrated textbook that tells the newcomer to the field everything they need to know to get started. Assuming little in the way of prior knowledge, the book covers the concepts behind the subject, its breadth, applications and the latest contemporary thinking in the area. It also includes coverage of the more important experimental and instrumental techniques needed by supramolecular chemists. The book has been thoroughly updated for this second edition. In addition to the strengths of the very popular first edition, this comprehensive new version expands coverage into a broad range of emerging areas. Clear explanations of both fundamental and nascent concepts are supplemented by up-to-date coverage of exciting emerging trends in the literature. Numerous examples and problems are included throughout the book. A system of “key references” allows rapid access to the secondary literature, and of course comprehensive primary literature citations are provided. A selection of the topics covered is listed below. Cation, anion, ion-pair and molecular host-guest chemistry Crystal engineering Topological entanglement Clathrates Self-assembly Molecular devices Dendrimers Supramolecular polymers Microfabrication Nanoparticles Chemical emergence Metal-organic frameworks Gels Ionic liquids Supramolecular catalysis Molecular electronics Polymorphism Gas sorption Anion-pinteractions Nanochemistry Supramolecular Chemistry is a must for both students new to the field and for experienced researchers wanting to explore the origins and wider context of their work. Review: "At just under 1000 pages, the second edition of Steed and Atwood's Supramolecular Chemistry is the most comprehensive overview of the area available in textbook form...highly recommended." —Chemistry World, August 2009




Core Concepts in Supramolecular Chemistry and Nanochemistry


Book Description

Supramolecular chemistry and nanochemistry are two strongly interrelated cutting edge frontiers in research in the chemical sciences. The results of recent work in the area are now an increasing part of modern degree courses and hugely important to researchers. Core Concepts in Supramolecular Chemistry and Nanochemistry clearly outlines the fundamentals that underlie supramolecular chemistry and nanochemistry and takes an umbrella view of the whole area. This concise textbook traces the fascinating modern practice of the chemistry of the non-covalent bond from its fundamental origins through to it expression in the emergence of nanochemistry. Fusing synthetic materials and supramolecular chemistry with crystal engineering and the emerging principles of nanotechnology, the book is an ideal introduction to current chemical thought for researchers and a superb resource for students entering these exciting areas for the first time. The book builds from first principles rather than adopting a review style and includes key references to guide the reader through influential work. supplementary website featuring powerpoint slides of the figures in the book further references in each chapter builds from first principles rather than adopting a review style includes chapter on nanochemistry clear diagrams to highlight basic principles




Trade Policy and Economic Integration in the Middle East and North Africa


Book Description

This important book examines the impact of recent changes in the world economy on trade policy within the MENA region and its economic relations with the rest of the world.




Organic Nanostructures


Book Description

Filling the need for a volume on the organic side of nanotechnology, this comprehensive overview covers all major nanostructured materials in one handy volume. Alongside metal organic frameworks, this monograph also treats other modern aspects, such as rotaxanes, catenanes, nanoporosity and catalysis. Detailed attention is paid to the chemistry, physics and materials science throughout, making this a definite must for all chemists.




Crop Production and Global Environmental Issues


Book Description

Meeting the world’s food security challenge will require a multi-national, collaborative effort to integrate the best research from science, engineering and socioeconomics so that technological advances can bring benefits where they are most needed. The present book covers the effect of major environmental problems on crop production and how to cope with these issues for sustainable agriculture and improvements of crops. The world’s population is predicted to hit 9.6 Billion by 2050, up from today’s total of nearly 7.3 Billion, and with it food demand is predicted to increase substantially. The post-war ‘second agricultural revolution’ in developed countries, and the ‘green revolution’ in developing nations in the mid- 1960s converted agricultural practices and elevated crop yields spectacularly, but the outcome is levelling off and will not meet projected demand. Simultaneously, crop production is affected by many other factors, including industrial pollution, overuse of fertilizers and insecticides, heavy metal and radiation stresses etc. It has been noted that many pests are becoming resistant to insecticides. Estimates vary, but around 25% of crops can be lost to pests and diseases. Climate change associated with agriculture is also a global issue. Agriculture is a significant contributor to greenhouse gases and is estimated to account for 10-12% of total greenhouse gas (GHG) emissions. Many of the issues highlighted are global problems and are addressed thoroug hly in this work.




Field Emission and Field Ionization


Book Description

Market: Students and researchers in vacuum and surface science, microscopy, and semiconductor physics. This definitive work was based on four lectures presented at Harvard University in 1958. When it was written, field emission was one of the few techniques available for surface studies and the attainment of ultra-high vacuum was a little-known art. Though more sophisticated treatments have since been developed, Gomer's pioneering work remains valid to this day.




Molecules at Work


Book Description

This book contains the contributions of selected young chemists from the field of nanotechnology and material sciences. The contributions are grouped under the following umbrella topics: Self assembly Nanomaterials Molecular Machinery This volume is an indispensable read for all materials scientists, organic, and inorganic chemists, Ph.D. students in chemistry and material sciences interested in seeing what tomorrow's chemistry will look like.




Dynamic Light Scattering


Book Description

In the twenty years since their inception, modern dynamic light-scattering techniques have become increasingly sophisticated, and their applications have grown exceedingly diverse. Applications of the techniques to problems in physics, chemistry, biology, medicine, and fluid mechanics have prolifer ated. It is probably no longer possible for one or two authors to write a monograph to cover in depth the advances in scattering techniques and the main areas in which they have made a major impact. This volume, which we expect to be the first of aseries, presents reviews of selected specialized areas by renowned experts. It makes no attempt to be comprehensive; it emphasizes a body of related applications to polymeric, biological, and colloidal systems, and to critical phenomena. The well-known monographs on dynamic light scattering by Berne and Pecora and by Chu were published almost ten years ago. They provided comprehensive treatments of the general principles of dynamic light scat tering and gave introductions to a wide variety of applications, but natu rally they could not treat the new applications and advances in older ones that have arisen in the last decade. The new applications include studies of interacting particles in solution (Chapter 4); scaling approaches to the dynamics of polymers, including polymers in semidilute solution (Chapter 5); the use of both Fabry-Perot interferometry and photon correlation spectroscopy to study bulk polymers (Chapter 6); studies of micelIes and microemulsions (Chapter 8); studies of polymer gels (Chapter 9).




Calixarene Complexes


Book Description

A growing interest has been devoted to the development of host systems for ionic and neutral species based on calixarenes. These cyclic oligomers show important host-guest properties, which has led to numerous applications in a broad range of fields, including organocatalysis, sensing, extraction and separation, and, more recently, biomedical applications. The relative ease of the functionalization of their upper and lower rims and the presence of a pre-organized cavity that is available in different sizes and conformations make calixarenes attractive building blocks for the construction of supramolecular assemblies. This book presents the most recent developments on the host-guest properties of calixarenes, as well as the new synthetic methods and applications.




High-Performance Thin-Layer Chromatography (HPTLC)


Book Description

The present edited book is the presentation of 18 in-depth national and international contributions from eminent professors, scientists and instrumental chemists from educational institutes, research organizations and industries providing their views on their experience, handling, observation and research outputs on HPTLC, a multi-dimensional instrumentation. The book describes the recent advancements made on TLC which have revolutionized and transformed it into a modern instrumental technique HPTLC. The book addresses different chapters on HPTLC fundamentals: principle, theory, understanding; instrumentation: implementation, optimization, validation, automation and qualitative and quantitative analysis; applications: phytochemical analysis, biomedical analysis, herbal drug quantification, analytical analysis, finger print analysis and potential for hyphenation: HPTLC future to combinatorial approach, HPTLC-MS, HPTLC-FTIR and HPTLC-Scanning Diode Laser. The chapters in the book have been designed in such away that the reader follows each step of the HPTLC in logical order.