Nucleation


Book Description

This book represents a detailed and systematic account of the basic principles, developments and applications of the theory of nucleation. The formation of new phases begins with the process of nucleation and is, therefore, a widely spread phenomenon in both nature and technology. Condensation and evaporation, crystal growth, electrodeposition, melt crystallization, growth of thin films for microelectronics, volcano eruption and formation of particulate matter in space are only a few of the processes in which nucleation plays a prominent role. The book has four parts, which are devoted to the thermodynamics of nucleation, the kinetics of nucleation, the effect of various factors on nucleation and the application of the theory to other processes, which involve nucleation. The first two parts describe in detail the two basic approaches in nucleation theory - the thermodynamic and the kinetic ones. They contain derivations of the basic and most important formulae of the theory and discuss their limitations and possibilities for improvement. The third part deals with some of the factors that can affect nucleation and is a natural continuation of the first two chapters. The last part is devoted to the application of the theory to processes of practical importance such as melt crystallization and polymorphic transformation, crystal growth and growth of thin solid films, size distribution of droplets and crystallites in condensation and crystallization. The book is not just an account of the status quo in nucleation theory - throughout the book there are a number of new results as well as extensions and generalisations of existing ones.




Electrocrystallization


Book Description

“Electrocrystallization is a particular case of a first order phase transition” and “Electrocrystallization is a particular case of electrochemical kinetics” are two statements that I have heard and read many times. I do not like them for a simple reason: it is annoying to see that the subject to which you have devoted more than 30 years of your life may be considered as a “particular case”. Therefore, I decided to write this book in which Electrocrystallization is the main subject. To become competent in the field of Electrocrystallization one should possess knowledge of Electrochemistry, Nucleation and Crystal Growth, which means knowledge of Physical Chemistry, Physics and Mathematics. That is certainly difficult and in most cases those who study Electrocrystallization are either more electrochemists, or more physical chemists, or more physicists, very often depending on whom has been their teacher. Of course, there are scientists who consider themselves equally good in all those fields. Very frequently they are, unfortunately, equally bad. The difference is essential but strange enough, it is sometimes not easy to realize the truth immediately.




Special Issues on Magnesium Alloys


Book Description

Magnesium is the lightest of all the metals and the sixth most abundant on Earth. Magnesium is ductile and the most machinable of all the metals. Magnesium alloy developments have traditionally been driven by requirements for lightweight materials to operate under increasingly demanding conditions (magnesium alloy castings, wrought products, powder metallurgy components, office equipment, nuclear applications, flares, sacrificial anodes for the protection of other metals, flash photography and tools). The biggest potential market for magnesium alloys is in the automotive industry. In recent years new magnesium alloys have demonstrated a superior corrosion resistance for aerospace and specialty applications. Considering the information above, special issues on magnesium alloys are exposed in this book: casting technology; surface modification of some special Mg alloys; protective carbon coatings on magnesium alloys; fatigue cracking behaviors of cast magnesium alloys and also, magnesium alloys biocompatibility as degradable implant materials.




Fluctuation Phenomena


Book Description

Studies in Statistical Mechanics, Volume VII: Fluctuation Phenomena Fluctuation explores different aspects of fluctuation behavior and their relation to microscopic processes and other phenomena, including the nucleation of a new phase following the quenching of a system into the coexistence region. It looks at phenomenological fluctuation theories, stochastic processes such as Markoff and momentless processes, and stochastic geometric aspects of amorphous solids. Comprised of five chapters, this volume begins with an overview of fluctuations and the Ehrenfest dog-flea model. It then turns to a discussion of density fluctuations in dilute gases, the Langevin theory of Brownian motion, and classical diffusion and random walks. It also systematically introduces the reader to the statistical mechanical theory of the kinetics of phase transitions, the molecular theory of metastability, and multidimensional continuous time random walks, along with the effect of boundaries and defects onf stochastic processes. In addition, it describes the phenomenological theory of the kinetics of nucleation and its application to nucleation, spinodal decomposition, and condensation. Other chapters focus on a stochastic model for the kinetics of phase transitions, the physical ideas used in theories of metastability, and the importance of dynamics in the study of metastability. The book explains how to estimate the escape rate and describes the statistical mechanics of clusters before concluding with a discussion of slowly-varying ensembles. This book is a valuable resource for students, physicists, and researchers who want to gain more knowledge and learn about statistical mechanics in general and fluctuation phenomena in particular.










Biological Crystallization


Book Description

For at least six hundred million years, life has been a fascinating laboratory of crystallization, referred to as biomineralization. During this huge lapse of time, many organisms from diverse phyla have developed the capability to precipitate various types of minerals, exploring distinctive pathways for building sophisticated structural architectures for different purposes. The Darwinian exploration was performed by trial and error, but the success in terms of complexity and efficiency is evident. Understanding the strategies that those organisms employ for regulating the nucleation, growth, and assembly of nanocrystals to build these sophisticated devices is an intellectual challenge and a source of inspiration in fields as diverse as materials science, nanotechnology, and biomedicine. However, “Biological Crystallization” is a broader topic that includes biomineralization, but also the laboratory crystallization of biological compounds such as macromolecules, carbohydrates, or lipids, and the synthesis and fabrication of biomimetic materials by different routes. This Special Issue collects 15 contributions ranging from biological and biomimetic crystallization of calcium carbonate, calcium phosphate, and silica-carbonate self-assembled materials to the crystallization of biological macromolecules. Special attention has been paid to the fundamental phenomena of crystallization (nucleation and growth), and the applications of the crystals in biomedicine, environment, and materials science.




Acoustic Emission and Critical Phenomena


Book Description

The Acoustic Emission (AE) technique uses ad hoc transducers to detect AE events caused by crack growth in structures under external loading. This technique is similar to the one employed in earthquake control, where seismic waves reach the monitoring stations placed on the surface of the Earth. And although they take place on different scales, the