Spectroscopy of the Excited State


Book Description

These proceedings report the lectures and seminars presented at the NATO Advanced Study Institute on "The Spectroscopy of the Excited State," held at Erice, Italy, June 9-24, 1975. This Institute was an activity of the International School of Atomic and Molecular Spectroscopy of the "Ettore Majorana" Centre for Scientific Culture. The Institute consisted of a series of lectures on the spectroscopic properties of materials in excited electronic states, that, starting at a fundamental level, finally reached the current level of research. The sequence of lectures and the organization of the material taught were in keeping with a didac tical presentation. In essence the course had the two-fold pur pose of organizing what was known on the subject, and updating the knowledge in the field. The formal lectures were complemented by seminars whose abstracts are also included in these proceedings. The proceedings report also the contributions sent by Professors R.G.W. Norrish and S. C1aesson who, unfortunately, were not able to come because of illness. A total of 62 participants and 7 lecturers came from the following countries: Belgium, Canada, Czechoslovakia, France, Germany, Israel, Italy, Japan, Netherlands, Norway, Pakistan, Poland, Sweden, Switzerland, the United Kingdom, the United States and Venezuela. The secretaries of the course were: A. La Francesca for the administrative aspects of the meeting and P.Papagiannakopou10s for the scientific aspects of the meeting.




Optical Properties of Excited States in Solids


Book Description

This book presents an account of the course "Optical Properties of Excited States in Solids" held in Erice, Italy, from June 16 to 3D, 1991. This meeting was organized by the International School of Atomic and Molecular Spectroscopy of the "Ettore Majorana" Centre for Scientific Culture. The purpose of this course was to present physical models, mathematical formalisms and experimental techniques relevant to the optical properties of excited states in solids. Some active physical species, such as ions or radicals, could survive indefinitely if they were completely 'isolated in space. Other active species, such as excited molecular and solid-state systems, are inherently unstable, even in isolation, due to the spontaneous mechanisms that may convert their excitation energies into radiation or heat. Physical parameters that may be used to characterize these excited systems are the localization or delocalization, and the coherence or incoherence, of their state excitations. In solids the excited states, whether they are localized (as for impurities in insulators) or delocalized (as they may occur in semiconductors), are relevant in several regards. Their de-excitation is extremely sensitive to the nature of the excitations of the systems, and a study of the de-excitation processes can yield a variety of information. For example, the excited states may represent the initial condition of the onset of such processes as Stokes-shifted emission, hot luminescence, symmetry-dependent Jahn-Teller and scattering processes, tunneling processes, energy transfer to like and unlike centers, superradiance, coherent radiation, and excited state absorption.







Higher Excited States of Polyatomic Molecules


Book Description

Higher Excited States of Polyatomic Molecules, Volume I focuses on the spectra in the vacuum-ultraviolet region between 50,000 and 100,000 cm-1. This book explores the higher excitations in molecules beyond 50,000 cm-1. Organized into three chapters, this volume starts with an overview of the excited-state properties of a molecule and the excited-state ionization potential. This book then proceeds with a discussion of the original classification of the properties as well as the types of excitations observed in the vacuum-ultraviolet. Other chapters discuss photoelectron spectroscopy, which is an independent, self-sustaining branch of molecular spectroscopy. This text examines as well the distinction between valence shell and Rydberg excitations. The final chapter deals with several topics, including the saturated molecules that are classified as having all valence electrons, the alkene absorption spectra, and the spectroscopic data on boron compounds. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.




Excited States


Book Description







Excited States and Photochemistry of Organic Molecules


Book Description

A significantly updated translation of Lichtabsorption und Photochemie Organischer Molekule, published by VCH in 1989. A graduate textbook that provides a qualitative description of electronic excitation in organic molecules and of the associated spectroscopy, photophysics, and photochemistry. The treatment is non- mathematical and emphasizes the use of simple qualitative models for developing an intuitive feeling for the course of photophysical and photochemical processes in terms of potential energy hypersurfaces. Special attention is paid to recent developments, particularly to the role of conical intersections. Annotation copyright by Book News, Inc., Portland, OR










Electron Spectroscopy


Book Description