Energetic Materials


Book Description

Advances in Quantum Chemistry presents surveys of current topics in this rapidly developing field that has emerged at the cross section of the historically established areas of mathematics, physics, chemistry, and biology. It features detailed reviews written by leading international researchers. This volume focuses on the theory of heavy ion physics in medicine. - This volume presents a series of articles concerning current important topics in quantum chemistry. The invited articles are written by the best people in the field




High Explosives, Propellants, Pyrotechnics


Book Description

This dictionary contains 739 entries with about 1400 references to the primary literature. Details on the composition, performance, sensitivity and other pertinent properties of Energetic Materials such as High Explosives, Propellants, Pyrotechnics, as well as important ingredients such as Oxidizers, Fuels, Binders, and Modifiers are given and presented partly in over 180 tables with more than 240 structural formulas . In detail the dictionary gives elaborate descriptions of 460 Chemical Substances 170 Pyrotechnic Compositions 360 High Explosive and Propellant Formulations In addition, the basic physical and thermochemical properties of 435 pure substances (elements & compounds) typically occuring as ingredients or reaction products are given too. 150 Figures, schemes and diagrams explain Applications, Test methods, Scientific facilities, and finally Individuals closely tied with the development and investigation of Energetic Materials. The book is intended for readers with a technical or scientific background, active in governmental agencies, research institutes, trade and industry, concerned with the procurement, development, manufacture, investigation and use of Energetic Materials, such as High Explosives, Propellants, Pyrotechnics, Fireworks and Ammunition. The book serves both as a daily reference for the experienced as well as an introduction for the newcomer to the field.




Static Compression of Energetic Materials


Book Description

Developing and testing novel energetic materials is an expanding branch of the materials sciences. Reaction, detonation or explosion of such materials invariably produce extremely high pressures and temperatures. To study the equations-of-state (EOS) of energetic materials in extreme regimes both shock and static high pressure studies are required. The present volume is an introduction and review of theoretical, experimental and numerical aspects of static compression of such materials. Chapter 1 introduces the basic experimental tool, the diamond anvil pressure cell and the observational techniques used with it such as optical microscopy, infrared spectrometry and x-ray diffraction. Chapter 2 outlines the principles of high-nitrogen energetic materials synthesis. Chapters 3 and 4, examine and compare various EOS formalisms and data fitting for crystalline and non-crystalline materials, respectively. Chapter 5 details the reaction kinetics of detonating energetic materials. Chapter 6 investigates the interplay between static and dynamic (shock) studies. Finally, Chapters 7 and 8 introduce numerical simulations: molecular dynamics of energetic materials under either hydrostatic or uni-axial stress and ab-inito treatments of defects in crystalline materials. This timely volume meets the growing demand for a state-of-the art introduction and review of the most relevant aspects of static compression of energetic materials and will be a valuable reference to researchers and scientists working in academic, industrial and governmental research laboratories.




Dislocations in Solids


Book Description

This is the first volume to appear under the joint editorship of J.P. Hirth and F.R.N. Nabarro. While Volume 11 concentrated on the single topic of dislocations and work hardening, the present volume spreads over the whole range of the study of dislocations from the application by Kléman and his colleagues of homotopy theory to classifying the line and point defects of mesomorphic phases to Chaudhri's account of the experimental observations of dislocations formed around indentations. Chapter 64, by Cai, Bulatove, Chang, Li and Yip, discusses the influence of the structure of the core of a dislocation on its mobility. The power of modern computation allows this topic to be treated from the first principles of electron theory, and with empirical potentials for more complicated problems. Advances in electron microscopy allow these theoretical predictions to be tested. In Chapter 65, Xu analyzes the emission of dislocations from the tip of a crack and its influence on the brittle to ductile transition. Again, the treatment is predominantly theoretical, but it is consistently related to the very practical example of alpha iron. In a dazzling interplay of experiment and abstract mathematics, Kléman, Lavrentovich and Nastishin analyze the line and point structural defects of the many mesomorphic phases which have become known in recent years. Chapter 67, by Coupeau, Girard and Rabier, is essentially experimental. It shows how the various modern techniques of scanning probe microscopy can be used to study dislocations and their interaction with the free surface. Chapter 68, by Mitchell and Heuer, considers the complex dislocations that can form in ceramic crystals on the basis of observations by transmission electron microscopy and presents mechanistic models for the motion of the dislocations in various temperature regimes. While the underlying aim of the study of dislocations in energetic crystals by Armstrong and Elban in Chapter 69 is to understand the role of dislocations in the process of detonation, it has the wider interest of studying dislocations in molecular crystals which are ``elastically soft, plastically hard, and brittle''. Chaudhri in Chapter 70 discusses the role of dislocations in indentation processes, largely on the basis of the elastic analysis by E.H. Yoffe. The special case of nanoindentations is treated only briefly.




Dislocations in Solids


Book Description

This is the first volume to appear under the joint editorship of J.P. Hirth and F.R.N. Nabarro. While Volume 11 concentrated on the single topic of dislocations and work hardening, the present volume spreads over the whole range of the study of dislocations from the application by Kléman and his colleagues of homotopy theory to classifying the line and point defects of mesomorphic phases to Chaudhri's account of the experimental observations of dislocations formed around indentations.Chapter 64, by Cai, Bulatove, Chang, Li and Yip, discusses the influence of the structure of the core of a dislocation on its mobility. The power of modern computation allows this topic to be treated from the first principles of electron theory, and with empirical potentials for more complicated problems. Advances in electron microscopy allow these theoretical predictions to be tested.In Chapter 65, Xu analyzes the emission of dislocations from the tip of a crack and its influence on the brittle to ductile transition. Again, the treatment is predominantly theoretical, but it is consistently related to the very practical example of alpha iron.In a dazzling interplay of experiment and abstract mathematics, Kléman, Lavrentovich and Nastishin analyze the line and point structural defects of the many mesomorphic phases which have become known in recent years.Chapter 67, by Coupeau, Girard and Rabier, is essentially experimental. It shows how the various modern techniques of scanning probe microscopy can be used to study dislocations and their interaction with the free surface.Chapter 68, by Mitchell and Heuer, considers the complex dislocations that can form in ceramic crystals on the basis of observations by transmission electron microscopy and presents mechanistic models for the motion of the dislocations in various temperature regimes.While the underlying aim of the study of dislocations in energetic crystals by Armstrong and Elban in Chapter 69 is to understand the role of dislocations in the process of detonation, it has the wider interest of studying dislocations in molecular crystals which are ``elastically soft, plastically hard, and brittle''.Chaudhri in Chapter 70 discusses the role of dislocations in indentation processes, largely on the basis of the elastic analysis by E.H. Yoffe. The special case of nanoindentations is treated only briefly.







Military Pyrotechnics


Book Description

This book covers military pyrotechnics characteristics, sensitivity, combustion, performance parameters, ingredients and their behaviour, various pyrotechnic compositions and their manufacturing methods, filling, pressing and assembly of ammunition and so forth. Divided into two broader sections, namely military pyrotechnic compositions and military pyrotechnic ammunitions and devices, it provides full spectrum of military pyrotechnics and a guide for all personnel involved with management of military pyrotechnic ammunitions and devices in design, production, inspection, training, and use. Features: Answers "know what", "know why "and "know how" of pyrotechnic compositions and pyrotechnic ammunitions and devices Explains various concepts and mechanisms of the military pyrotechnics Deliberates on role and characteristics of pyrotechnic compositions and its classification Discusses various factors affecting performance and some differences in military pyrotechnics Describes various methods of initiation of ignition in ammunition Elucidates basic requirements of pyrotechnic ammunitions, its development and life cycle of ammunition lots Provides classification, division, shelf life, compatibility and nomenclature of ammunitions and devices Reviews test/proof requirements of ammunitions and devices, deployment and functioning, defect classification, sampling plan and acceptance criteria Explores latest trends in 'green pyrotechnics' for environment- friendly military pyrotechnics




Synthesis, Characterization and Properties of Energetic/reactive Nanomaterials


Book Description

The advent of nanomaterials has introduced a new dimension in applications of energetic and reactive materials. A fundamental understanding of their synthesis mechanisms, atomic- and molecular-scale structural characteristics, and an evaluation of properties combined with modeling of the limits to those properties are required to realize the full potential of energetic and reactive nanomaterials. Many techniques have been recently developed that make it possible to exploit the benefits of the "nano" structure and design materials with desired energy release rates and energy densities, while they also improve their safety, reliability and load-bearing capability. Advances in modeling and characterization have made it possible to determine mechanisms controlling the thermal, chemical and mechanical behavior of nanomaterials. This volume brings together researchers from around the world to assess fundamental studies on synthesis, characterization of structure, and evaluation of properties of energetic/reactive nanomaterials. Applications such as new propellant formulations, underwater detonation developments, biomedical research, and combustion of nanolayered metal films for cladding materials are featured. Topics include: applications and toxicology; synthesis; characterization; characterization and theory; theory and modeling; and general discussion.




Advances in Quantative Structure - Property Relationships


Book Description

The object of this series is to provide interesting and timely reviews covering all aspects of the field. It is our hope that this will encourage the transfer of new methods, techniques, and parameterizations from the field in which they were developed to other areas that can make good use of them.·Quantitative Structure Property Relationships (QSPR) have developed into a major method of chemical research in many scientific disciplines·Provides much needed cross fertilization between disciplines researching QSPR




High-Pressure Shock Compression of Solids III


Book Description

Developments in experimental methods are providing an increasingly detailed understanding of shock compression phenomena on the bulk, intermediate, and molecular scales. This third volume in a series of reviews of the curent state of knowledge covers several diverse areas. The first group of chapters addresses fundamental physical and chemical aspects of the response of condensed matter to shock comression: equations of state, molecular-dynamic analysis, deformation of materials, spectroscopic methods. Two further chapters focus on a particular group of materials: ceramics. Another chapter discusses shock-induced reaction of condensed-phase explosives. And a final pair of chapters considers shock phenomena at low stresses from the point of view of continuum mechanics.