Chemistry of Zeolites and Related Porous Materials


Book Description

Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial uses This book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.




Nanomaterials for Air Remediation


Book Description

Nanomaterials for Air Remediation provides a comprehensive description of basic knowledge and current research progress in the field of air treatment using nanomaterials. The book explores how nanomaterials are used in various air remediation techniques, including advanced oxidation processes, biological processes, and filtration. It also covers their combined use as nanocatalysts, nanoantibiotics, nanoadsorbents, nanocontainers, nanofiltrations and nanosensors. Major challenges to using nanomaterials for improving air quality on a mass scale, both practical and regulatory, are also presented. This is an important resource for materials scientists and environmental engineers who are looking to understand how nanotechnology is used to enhance air quality.




Fabrication and Functionalization of Advanced Tubular Nanofibers and their Applications


Book Description

Fabrication and Functionalization of Advanced Tubular Nanofibers and their Applications describes the synthesis, preparation and characterization of carbon-based tubular nanofibers and their applications in environmental protection and new energy sources. The book explores novel strategies for the preparation of carbon tubular nanofibers and explains how they have been used to great effect in a range of applications, including energy and healthcare. The processing-structure-property relationship in functional inorganic/organic materials is examined at the nano-level, explaining where interesting electronic, magnetic, optical, mechanical or catalytic and therapeutic properties are derived. Covering everything from the basics to their use in practice, including the synthetic procedure and characterization, this book is the perfect guide for anyone interested in the design of nanomaterials for advanced applications. Nanomaterial science is a relatively young and rapidly developing discipline that includes aspects of physics, chemistry and biology and is finding applications in some of mankind's greatest current challenges. - Describes how to produce superior tubular nanofiber performance in one or more characteristics - Addresses important advances in the synthesis, processing and surface modification of new materials - Explains innovative applications of tubular nanofibers in environmental and biotechnology applications




Metal-Organic Framework Materials


Book Description

Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc




Porous Materials


Book Description

Engineers and scientists alike will find this book to be an excellent introduction to the topic of porous materials, in particular the three main groups of porous materials: porous metals, porous ceramics, and polymer foams. Beginning with a general introduction to porous materials, the next six chapters focus on the processing and applications of each of the three main materials groups. The book includes such new processes as gel-casting and freeze-drying for porous ceramics and self-propagating high temperature synthesis (SHS) for porous metals. The applications discussed are relevant to a wide number of fields and industries, including aerospace, energy, transportation, construction, electronics, biomedical and others. The book concludes with a chapter on characterization methods for some basic parameters of porous materials. Porous Materials: Processing and Applications is an excellent resource for academic and industrial researchers in porous materials, as well as for upper-level undergraduate and graduate students in materials science and engineering, physics, chemistry, mechanics, metallurgy, and related specialties. - A comprehensive overview of processing and applications of porous materials – provides younger researchers, engineers and students with the best introduction to this class of materials - Includes three full chapters on modern applications - one for each of the three main groups of porous materials - Introduces readers to several characterization methods for porous materials, including methods for characterizing pore size, thermal conductivity, electrical resistivity and specific surface area




Covalent Organic Frameworks


Book Description

Rational synthesis of extended arrays of organic matter in bulk, solution, crystals, and thin films has always been a paramount goal of chemistry. The classical synthetic tools to obtain long-range regularity are, however, limited to noncovalent interactions, which usually yield structurally more random products. Hence, a combination of porosity and regularity in organic covalently bonded materials requires not only the design of molecular building blocks that allow for growth into a nonperturbed, regular geometry but also a condensation mechanism that progresses under reversible, thermodynamic, self-optimizing conditions. Covalent organic frameworks (COFs), a variety of 2D crystalline porous materials composed of light elements, resemble an sp2-carbon-based graphene sheet but have a different molecular skeleton formed by orderly linkage of building blocks to constitute a flat organic sheet. COFs have attracted considerable attention in the past decade because of their versatile applications in gas storage and separation, catalysis, sensing, drug delivery, and optoelectronic materials development. Compared to other porous materials, COFs allow for atomically precise control of their architectures by changing the structure of their building blocks, whereby the shapes and sizes of their pores can be well-tuned. Covalent Organic Frameworks is a compilation of different topics in COF research, from COF design and synthesis, crystallization, and structural linkages to the theory of gas sorption and various applications of COFs, such as heterogeneous catalysts, energy storage (e.g., semiconductors and batteries), and biomedicine. This handbook will appeal to anyone interested in nanotechnology and new materials of gas adsorption and storage, heterogeneous catalysts, electronic devices, and biomedical devices.




Porous Ceramic Materials


Book Description

Fabrication, Characterization, Applications




Nanoporous Materials: Science And Engineering


Book Description

Porous materials are of scientific and technological importance because of the presence of voids of controllable dimensions at the atomic, molecular, and nanometer scales, enabling them to discriminate and interact with molecules and clusters. Interestingly the big deal about this class of materials is about the “nothingness” within — the pore space. International Union of Pure and Applied Chemistry (IUPAC) classifies porous materials into three categories — micropores of less than 2 nm in diameter, mesopores between 2 and 50 nm, and macropores of greater than 50 nm. In this book, nanoporous materials are defined as those porous materials with pore diameters less than 100 nm.Over the last decade, there has been an ever increasing interest and research effort in the synthesis, characterization, functionalization, molecular modeling and design of nanoporous materials. The main challenges in research include the fundamental understanding of structure-property relations and tailor-design of nanostructures for specific properties and applications. Research efforts in this field have been driven by the rapid growing emerging applications such as biosensor, drug delivery, gas separation, energy storage and fuel cell technology, nanocatalysis and photonics. These applications offer exciting new opportunities for scientists to develop new strategies and techniques for the synthesis and applications of these materials.This book provides a series of systematic reviews of the recent developments in nanoporous materials. It covers the following topics: (1) synthesis, processing, characterization and property evaluation; (2) functionalization by physical and/or chemical treatments; (3) experimental and computational studies on fundamental properties, such as catalytic effects, transport and adsorption, molecular sieving and biosorption; (4) applications, including photonic devices, catalysis, environmental pollution control, biological molecules separation and isolation, sensors, membranes, hydrogen and energy storage, etc./a




Introduction to Reticular Chemistry


Book Description

A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.




Materials for Energy


Book Description

Discusses a wide range of material types, such as nanomaterials, carbonaceous electrocatalysts and electrolytes, thin films, phase change materials, 2D energy materials, triboelectric materials, and membrane materials Describes such applications as flexible energy storage devices, sensors, energy storage batteries, fuel and solar cells, photocatalytic wastewater treatment, and more Aimed at researchers and technologists working to solve alternative energy issues