Styrene Production from Propylene & Ethylbenzene - Cost Analysis - Styrene E21A


Book Description

This report presents a cost analysis of Styrene production from chemical grade (CG) propylene and ethylbenzene. The process examined is a propylene oxide/styrene monomer (POSM) process similar to LyondellBasell technology. In this process, ethylbenzene is oxidized to produce ethylbenzene hydroperoxide, which reacts with propylene to produce Styrene and propylene oxide products. This report was developed based essentially on the following reference(s): "Propylene Oxide", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Propene, Ethylbenzol, Oxidation, Epoxidation, EBHP, Phenylethene, POSM




Chemical Process Simulation and the Aspen HYSYS Software


Book Description

The document "Chemical Process Simulation and the Aspen HYSYS Software", Version 7.3, is a self-paced instructional manual that aids students in learning how to use a chemical process simulator and how a process simulator models material balances, phase equilibria, and energy balances for chemical process units. The student learning is driven by the development of the material and energy requirements for a specific chemical process flowsheet. This semester-long, problem-based learning activity is intended to be a student-based independent study, with about two-hour support provided once a week by a student teaching assistant to answer any questions.Chapter 1 of this HYSYS manual provides an overview of the problem assignment to make styrene monomer from toluene and methanol. Chapter 2 presents ten tutorials to introduce the student to the HYSYS simulation software. The first six of these tutorials can be completed in a two-week period for the introductory chemical engineering course. The other four are intended for the senior-level design course. Chapter 3 provides five assignments to develop the student's abilities and confidence to simulate individual process units using HYSYS. These five assignments can be completed over a three-week period. Chapter 4 contains seven assignments to develop the styrene monomer flowsheet. These seven assignments can be completed over a seven-week period. In Chapter 4, each member of a four-member team begins with the process reactor unit for a specifically-assigned temperature, molar conversion, and yield. Subsequent assignments increase the complexity of the flowsheet by adding process units, one by one, until the complete flowsheet with recycle is simulated in HYSYS. The team's objective is to determine the operating temperature for the reactor, such that the net profit is maximized before considering federal taxes. Finally, eleven appendices provide mathematical explanations of how HYSYS does its calculations for various process units-process stream, stream tee, stream mixer, pump, valve, heater/cooler, chemical reactor, two-phase separator, three-phase separator, component splitter, and simple distillation.This HYSYS manual can be used with most textbooks for the introductory course on chemical engineering, like Elementary Principles of Chemical Processes (Felder and Rousseau, 2005), Basic Principles and Calculations in Chemical Engineering (Himmelblau and Riggs, 2004), or Introduction to Chemical Processes: Principles, Analysis, Synthesis (Murphy, 2007). It can also be used as a refresher for chemical engineering seniors in their process engineering design course. Because the HYSYS manuscript was compiled using Adobe Acrobat(r), it contains many web links. Using a supplied web address and Acrobat Reader(r), students can electronically access the web links that appear in many of the chapters. These web links access Aspen HYSYS(r), Acrobat PDF(r), Microsoft Word(r), and Microsoft Excel(r) files that appear in many of chapters. Students can view but not copy or print the electronic version of the HYSYS manual.




Springer Handbook of Mechanical Engineering


Book Description

This resource covers all areas of interest for the practicing engineer as well as for the student at various levels and educational institutions. It features the work of authors from all over the world who have contributed their expertise and support the globally working engineer in finding a solution for today‘s mechanical engineering problems. Each subject is discussed in detail and supported by numerous figures and tables.




Styrene Production from Ethane & Benzene - Cost Analysis - Styrene E31A


Book Description

This report presents a cost analysis of Styrene production from ethane and benzene. The process examined is based on concepts proposed in patents issued to Dow and Snamprogetti. In this process, ethylbenzene (EB) is first generated from benzene feedstock and recycled ethylene. Then, fresh ethane and the EB are fed to a dehydrogenation reactor to simultaneously form ethylene, which is recycled, and Styrene as final product. Pure hydrogen is also generated as by-product. This report was developed based essentially on the following reference(s): Keywords: Styrene Monomer, SM, Ethylbenzene, Ethylene, Benzene, Alkylation, Dow, Snamprogetti




Medicinal Chemistry and Pharmacological Potential of Fullerenes and Carbon Nanotubes


Book Description

Fullerenes and nanotubes are two classes of carbon structures or allotropes, which were discovered about 17 years ago. Since that time, many chemical derivatives have been synthesized using fullerenes and nanotubes as building blocks. Particularly promising was the theory that the chemical properties of fullerenes, and certain derivatives, made them likely candidates for anticancer drugs, inhibitors of viruses such as HIV, or even as anti-bacterials. Their cyctotoxicity can also be controlled by specific circumstances. In addition, the funtionalization of nanotubes has not only produced relatively simple derivatives, but also complex hybrids with biological macromolecules, which show unique supramolecular architecture and which are promising in many medical applications. The application of fullerenes and nanotubes in medicine is at the frontier of our knowledge, thus the work in this field represents the basis for future novel developments.




Styrene Production from Ethylbenzene - Cost Analysis - Styrene E11A


Book Description

This report presents a cost analysis of Styrene production from ethylbenzene The process examined is a catalytic dehydrogenation process. This report was developed based essentially on the following reference(s): Keywords: Styrene Monomer, SM, Ethylbenzene, CB&I Lummus, UOP, Classic SM, SMART SM, TOTAL, Badger




Zeolite Microporous Solids: Synthesis, Structure, and Reactivity


Book Description

Intensive research on zeolites, during the past thirty years, has resulted in a deep understanding of their chemistry and in a true zeolite science, including synthesis, structure, chemical and physical properties, and catalysis. These studies are the basis for the development and growth of several industrial processes applying zeolites for selective sorption, separation, and catalysis. In 1983, a NATO Advanced Study Institute was organized in Alcabideche (portugal) to establish the State-of-the-Art in Zeolite Science and Technology and to contribute to a better understanding of the structural properties of zeolites, the configurational constraints they may exert, and their effects in adsorption, diffusion, and catalysis. Since then, zeolite science has witnessed an almost exponential growth in published papers and patents, dealing with both fundamentals issues and original applications. The proposal of new procedures for zeolite synthesis, the development of novel and sophisticated physical techniques for zeolite characterization, the discovery of new zeolitic and related microporous materials, progresses in quantum chemistry and molecular modeling of zeolites, and the application of zeolites as catalysts for organic reactions have prompted increasing interest among the scientific community. An important and harmonious interaction between various domains of Physics, Chemistry, and Engineering resulted therefrom.




Handbook of Engineering Practice of Materials and Corrosion


Book Description

This handbook is an in-depth guide to the practical aspects of materials and corrosion engineering in the energy and chemical industries. The book covers materials, corrosion, welding, heat treatment, coating, test and inspection, and mechanical design and integrity. A central focus is placed on industrial requirements, including codes, standards, regulations, and specifications that practicing material and corrosion engineers and technicians face in all roles and in all areas of responsibility. The comprehensive resource provides expert guidance on general corrosion mechanisms and recommends materials for the control and prevention of corrosion damage, and offers readers industry-tested best practices, rationales, and case studies.




Green Chemistry


Book Description

The history of environmental protection has dealt with hazardous substances by cleaning them up or treating them after the substances have formed. Green Chemistry, however, designs products and processes so that no hazardous materials are used or made in the first place. With applications fromplastic to paints, from automobiles to pharmaceuticals, Green Chemistry is revolutionising science and industry and its impact on the environment.




Biopolymer-Based Formulations


Book Description

Biopolymer-Based Formulations: Biomedical and Food Applications presents the latest advances in the synthesis and characterization of advanced biopolymeric formulations and their state-of-the-art applications across biomedicine and food science. Sections cover the fundamentals, applications, future trends, environmental, ethical and medical considerations, and biopolymeric architectures that are organized in nano, micro and macro scales. The final section of the book focuses on novel applications and recent developments. This book is an essential resource for researchers, scientists and advanced students in biopolymer science, polymer science, polymer chemistry, polymer composites, plastics engineering, biomaterials, materials science, biomedical engineering, and more. It will also be of interest to R&D professionals, scientists and engineers across the plastics, food, biomedical and pharmaceutical industries. - Provides in-depth coverage of methods for the characterization of the physical properties of biopolymeric architectures - Supports a range of novel applications, including scaffolds, implant coatings, drug delivery, and nutraceutical encapsulation systems - Includes the use of experimental data and mathematical modeling, thus enabling the reader to analyze and compare the properties of different polymeric gels