Zintl Ions


Book Description

R. Bruce King: Structure and Bonding in Zintl Ions and Related Main Group Element Clusters Stefanie Gärtner, Nikolaus Korber: Polyanions of Group 14 and Group 15 Elements in Alkali and Alkaline Earth Metal Solid State Compounds and Solvate Structures Bryan Eichhorn, Sanem Kocak: Dynamic Properties of the Group 14 Zintl Ions and Their Derivatives Thomas F. Fässler: Relationships between soluble Zintl anions, ligand-stabilized cage compounds, and intermetalloid clusters of tetrel (Si – Pb) and pentel (P – Bi) elements Gerasimos S. Armatas, Mercouri Kanatzidis: Germanium-Based Porous Semiconductors from Molecular Zintl Anions




Physical Metallurgy and processing of Intermetallic Compounds


Book Description

The attractive physical and mechanical properties of ordered intermetallic alloys have been recognized since early in this century. However, periodic attempts to develop intermetallics for structural applications were unsuc cessful, due in major part to the twin handicaps of inadequate low-temper ature ductility or toughness, together with poor elevated-temperature creep strength. The discovery, in 1979, by Aoki and Izumi in Japan that small additions of boron caused a dramatic improvement in the ductility of Ni3Al was a major factor in launching a new wave of fundamental and applied research on intermetallics. Another important factor was the issuance in 1984 of a National Materials Advisory Board reported entitled "Structural Uses for Ductile Ordered Alloys," which identified numerous potential defense-related applications and proposed the launching of a coordinated development program to gather engineering property and processing data. A substantial research effort on titanium aluminides was already underway at the Air Force Materials Laboratory at Wright Patterson Air Force Base in Ohio and, with Air Force support, at several industrial and university laboratories. Smaller programs also were under way at Oak Ridge National Laboratory, under Department of Energy sponsorship. These research efforts were soon augmented in the United States by funding from Department of Defense agencies such as Office of Naval Research and Air Force Office of Scientific Research, and by the National Science Foundation.




Inorganic Reactions and Methods, The Formation of the Bond to Hydrogen (Part 2)


Book Description

For the first time the discipline of modern inorganic chemistry has been systematized according to a plan constructed by a council of editorial advisors and consultants, among them three Nobel laureates (E.O. Fischer, H. Taube and G. Wilkinson). Rather than producing a collection of unrelated review articles, the series creates a framework which reflects the creative potential of this scientific discipline. Thus, it stimulates future development by identifiying areas which are fruitful for further research. The work is indexed in a unique way by a structured system which maximizes its usefulness to the reader. It augments the organization of the work by providing additional routes of access for specific compounds, reactions and other topics.




Handbook on the Physics and Chemistry of Rare Earths


Book Description

Handbook on the Physics and Chemistry of Rare Earths: Including Actinides, Volume 64, the latest release in this continuous series that covers all aspects of rare earth science, including chemistry, life sciences, materials science and physics, presents interesting chapters on a variety of topics, with this release including sections on Structure and properties of Ln2M3Ge5 compounds, Giant magnetocaloric effect materials, Lanthanide-based single-molecule magnets, and Magnetic Refrigeration with Lanthanide-Based Materials. - Presents up-to-date overviews and new developments in the field of rare earths, covering both their physics and chemistry - Contains individual chapters that are comprehensive and broad, along with critical reviews - Provides contributions from highly experienced, invited experts







Intermetallics


Book Description

Intermetallic compounds play an extraordinary role in daily life for construction materials and well-defined functions that are based on their specific chemical and physical properties, e.g. magnetism and superconductivity. High-tech materials are meanwhile indispensable in our technology-driven information society. The Periodic Table comprises more than 80 metallic elements which offer an incredible potential for formation of binary, ternary and even multinary intermetallic compounds with peculiar crystal structures and properties. The present textbook introduces into the basics of intermetallic chemistry with an emphasis on crystal chemistry and selected chemical and physical properties.













Intermetallics Research Progress


Book Description

Intermetallics is concerned with all aspects of ordered chemical compounds between two or more metals and notably with their applications. This book covers new and important research on the crystal chemistry and bonding theory of intermetallics; determination and analysis of phase diagrams; the nature of superlattices, antiphase domains and order-disorder transitions; the geometry and dynamics of dislocations and related defects in intermetallics; theory and experiments relating to flow stress, work-hardening, fatigue and creep; response of deformed intermetallics to annealing; magnetic and electrical properties of intermetallics; structure and properties of grain and interphase boundaries; the effect of deviations from stoichiometry on physical and mechanical properties; crystallisation of intermetallics from the melt or amorphous precursors.