Sulfur, Energy, and Environment


Book Description

Sulfur, Energy, and Environment is a guide to the properties of sulfur; its three important compounds; and a review of the production, use, and recovery of sulfur in relation to energy production and environmental protection. After a brief introduction to the history of sulfur, the chemical properties of the element and some important compounds are reviewed, using common analytical methods. Sulfur is a strategic chemical in many modern applications and may make headway into high-volume non-chemical uses as it is being modified according to our changing technology and needs. The sources of sulfur and where it frequently occurs is explained. This discussion is followed by citing reviews of the four most important cycles, that is, the global sulfur cycle, hydrosphere, atmospheric sulfur budget, and the anthropogenic sulfur cycle. Sulfur production methods, coal combustion chemistry, and flue gas desulfurization are then described. The many uses of sulfur are described, including in medicine, agriculture, chemical industry, and the plastic industry. However, throughout the production of sulfur, problems affecting the environment occur, so environmental control and legislation are also discussed. Finally, the trends of sulfur research, production, use and recovery, role of chemistry, and the future overall area where science, energy, chemistry, and the environment exist together are presented. Chemists and chemistry students, industrialists, and environmental planners will find this guide to sulfur helpful. Lecturers in chemistry and researchers in the many fields of application of sulfur will likewise benefit from it.




Handbook of Coal Analysis


Book Description

All the guidance needed to test coal and analyze the results With the skyrocketing costs of most fuel sources, government, industry, and consumers are taking a greater interest in coal, an abundant and inexpensive alternative, which has been made more environmentally friendly through new technology. Published in response to this renewed interest, Handbook of Coal Analysis provides readers with everything they need to know about testing and analyzing coal. Moreover, it explains the meaning of test results and how these results can predict coal behavior and its corresponding environmental impact during use. The thorough coverage of coal analysis includes: * Detailed presentation of necessary standard tests and procedures * Explanation of coal behavior relative to its usage alongside the corresponding environmental issues * Coverage of nomenclature, terminology, sampling, and accuracy and precision of analysis * Step-by-step test method protocols for proximate analysis, ultimate analysis, mineral matter, physical and electrical properties, thermal properties, mechanical properties, spectroscopic properties, and solvent properties * Emphasis on relevant American Society for Testing and Materials (ASTM) standards and test methods, including corresponding International Organization for Standardization (ISO) and British Standards Institution (BSI) test method numbers To assist readers in understanding the material, a glossary of terms is provided. Each term is defined in straightforward language that enables readers to better grasp complex concepts and theory. References at the end of each chapter lead readers to more in-depth discussions of specialized topics. This is an essential reference for analytical chemists, process chemists, and engineers in the coal industry as well as other professionals and researchers who are looking to coal as a means to decrease dependence on foreign oil sources and devise more efficient, cleaner methods of energy production.







An Introduction to Air Chemistry


Book Description

An Introduction to Air Chemistry serves as a textbook on air chemistry and covers topics such as chemical principles, sampling and collection, treatment of data, and special methods of analysis. The atmospheric chemistry of sulfur compounds is also discussed, together with nitrogen compounds and ozone, aerosols, and carbon compounds. This book is comprised of nine chapters and begins with a review of the relevant chemical and meteorological principles. The general methods for obtaining and handling air chemical data are then described, followed by a discussion on three classes of chemical compounds that are important in any consideration of trace constituents of the atmosphere, namely, sulfur compounds, carbon compounds, and nitrogen compounds and ozone. Significant atmospheric reactions, the global budgets, and selected methods of analysis for these compounds are considered. The final chapter examines some of the physical characteristics of aerosols. This monograph will be a valuable resource for upper-level undergraduate and graduate-level students of analytical chemistry, meteorology, oceanography, and civil engineering, as well as for laboratory chemists, meteorologists, physical scientists, and technicians.




Reactions of Organosulfur Compounds


Book Description

Organic Chemistry, Volume 37: Reactions of Organosulfur Compounds covers the basics of organosulfur chemistry and the characteristics of organically bound sulfur, with an emphasis on reactions, particularly those of synthetic utility. The book discusses the preparation, nature, stereochemical aspects, reactions, and the kinetic and thermodynamic assessment of the stability of sulfur-containing carbanions; the preparation and reactions of sulfur ylides; and the preparation, assessment of stability, and reactions of sulfur-containing carbocations. The text also describes preparation, assessment of stability, nature, and reactions of sulfur-containing radicals, organosulfur carbenes, and carbenoids; as well as the the pericyclic reactions of organosulfur compounds. Chemists, biochemists, and students taking related courses will find the book useful.




The Analytical Chemistry of Silicones


Book Description

High-Resolution Solid-State NMR of Silicates and Zeolites Gunter Engelhardt and Dieter Michel "I strongly recommend this book as an important reference for scientists concerned with the structural properties of siliceous materials." --Applied Spectroscopy This well-organized and up-to-date text gives a thorough account of the wide range of applications of multinuclear high-resolution solid-state NMR spectroscopy in silicate and zeolite science, with emphasis on the kinds of chemical information retrievable from NMR experiments. 1988 (0 471-91597-1) 485 pp. The Chemistry of Silica Solubility, Polymerization, Colloid and Surface Properties, and Biochemistry Ralph K. Iler A major component of the earth's solid surface and the constituent of sand, silica--an ageless natural staple--is also integral to industries as diverse as chemistry, biology, medicine, agriculture, metallurgy, and mining. This landmark reference details the chemistry surrounding the research and development of silica as well as information on its production and production control. 1979 (0 471-02404-X) 866 pp. The Chemistry of Organic Silicon Compounds Parts 1 and 2 Edited by Saul Patai and Zvi Rappoport "This volume will probably become the first reference consulted for C-Si chemistry." --Choice This authoritative account of organic compounds containing carbon-silicon bonds brings specialists up-to-date to the field's latest innovative turns. The emphasis in this compilation of studies--from 17 prominent researchers--is on small molecules, single bonds, analysis, structure, synthesis, spectroscopy, and reaction mechanisms. Part 1:1989 (0 471-91441-X) 892 pp. Part 2:1989 (0 471-91992-6) 1,668 pp.