The Chemistry of Radical Polymerization


Book Description

This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.




Handbook of Radical Polymerization


Book Description

Klassische und moderne Verfahren der radikalischen Polymerisation: In diesem handlichen Band finden Sie Antworten auf theoretische und praktische Fragen. Neben grundlegenden Ausführungen zur Einteilung radikalischer Polymere sind Angaben über die wichtigsten experimentellen Verfahren zur Synthese, Reinigung und Charakterisierung von Polymeren enthalten. Interessante Zugabe: ein Abriß der Geschichte der Radikalkettenpolymerisation.




Handbook of Free Radical Initiators


Book Description

Free radical initiators–chemical molecules which easily decompose into free radicals–serve as reactive intermediates in synthetic methodologies such as organic and polymer synthesis as well as in technological processes, oligomerization, network formation, and kinetic research. The Handbook of Free Radical Initiators presents an up-to-date account of the physicochemical data on radical initiators and reactions of radical generation. Individual chapters include: Dialkyl Peroxides and Hydroperoxides Diacyl Peroxides, Peresters, and Organic Polyoxides Azo-Compounds Bimolecular Reactions of Free Radical Generation by Ozone, Dioxygen, Hydroperoxides, and Haloid Molecules Free Radical Abstraction Reactions Free Radical Addition Reactions Free Radical Recombination and Disproportoination Reactions Professionals and academic researchers in chemical engineering, pharmaceuticals, biotechnology, plastics, and rubbers will find the Handbook of Free Radical Initiators to be a distinguished, vital resource.




Handbook of Polymer Synthesis, Characterization, and Processing


Book Description

Covering a broad range of polymer science topics, Handbook of Polymer Synthesis, Characterization, and Processing provides polymer industry professionals and researchers in polymer science and technology with a single, comprehensive handbook summarizing all aspects involved in the polymer production chain. The handbook focuses on industrially important polymers, analytical techniques, and formulation methods, with chapters covering step-growth, radical, and co-polymerization, crosslinking and grafting, reaction engineering, advanced technology applications, including conjugated, dendritic, and nanomaterial polymers and emulsions, and characterization methods, including spectroscopy, light scattering, and microscopy.




Handbook of Vinyl Polymers


Book Description

Radical polymerization is one of the most widely used means of producing vinyl polymers, supporting a myriad of commercial uses. Maintaining the quality of the critically acclaimed first edition, the Handbook of Vinyl Polymers: Radical Polymerization, Process, and Technology, Second Edition provides a fully updated, single-volume source on t




Fundamentals of Controlled/Living Radical Polymerization


Book Description

Controlled/living radical polymerization (CRP) has revolutionized and revitalized the field of synthetic polymer chemistry over the last twenty years as it is now possible to prepare a wide variety of previously inaccessible macromolecules under relatively mild conditions. Fundamentals of Controlled/Living Radical Polymerization provides an in-depth coverage of the essential chemical principles that enable and govern each of the CRP methods. The book starts with a brief historical overview of the major findings in polymer science which eventually led to the development of living ionic and living radical systems. It then goes on to introduce the main CRP techniques including their mechanistic understanding. The book also provides the information needed to select the appropriate reagents and conditions to conduct various CRP methods in a practical setting. Therefore, in addition to a newcomer gaining an appreciation for what has already been accomplished, the reader will be armed with the tools needed to begin independent research. Fundamentals of Controlled/Living Radical Polymerization provides essential insight into a rapidly growing field that goes beyond a simple literature review of the area. Written by leading experts in the field, the book is an indispensible resource for all researchers, instructors, and students in polymer chemistry.




Principles of Polymer Chemistry


Book Description

This successful textbook undergoes a change of character in the third edition. Where earlier editions covered organic polymer chemistry, the third edition covers both physical and organic chemistry. Thus kinetics and thermodynamics of polymerization reactions are discussed. This edition is also distinct from all other polymer textbooks because of its coverage of such currently hot topics as photonic polymers, electricity conducting polymers, polymeric materials for immobilization of reagents and drug release, organic solar cells, organic light emitting diodes. This textbook contains review questions at the end of every chapter, references for further reading, and numerous examples of commercially important processes.




The Chemistry of Polymers


Book Description

A concise introductory text written from an applied angle, primarily for recent graduates now working in industry who haven't previously studied polymer chemistry. Available in the US from CRC Press. Annotation copyrighted by Book News, Inc., Portland, OR




Handbook of RAFT Polymerization


Book Description

Spanning the entire field from fundamentals to applications in material science, this one-stop source is the first comprehensive reference for polymer, physical and surface chemists, materials scientists, chemical engineers, and those chemists working in industry. From the contents: * Introduction: Living Free Radical Polymerization and the RAFT Process * Fundamental Structure-Reactivity Correlations Governing the RAFT Process * Mechanism and Kinetics * The RAFT Process as a Kinetic Tool * Theory and Practice in Technical Applications * RAFT Polymerization in Bulk and Organic Solvents, as well as Homogeneous Aqueous Systems * Emulsion and Mini-Emulsion Polymerization * Complex Architecture Design * Macromolecular Design via the Interchange of Xanthates * Surface Modification * Stability and Physical Properties of RAFT Polymers * Novel Materials: From Drug Delivery to Opto-Electronics * Outlook and Future Developments




Fundamentals of Polymerization


Book Description

Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.