Variety in Coordination Modes of Ligands in Metal Complexes
Author : Shinʼichi Kawaguchi
Publisher : Springer
Page : 152 pages
File Size : 13,98 MB
Release : 1988
Category : Science
ISBN :
Author : Shinʼichi Kawaguchi
Publisher : Springer
Page : 152 pages
File Size : 13,98 MB
Release : 1988
Category : Science
ISBN :
Author : Benjamin Mogesa
Publisher :
Page : 0 pages
File Size : 33,52 MB
Release : 2014
Category :
ISBN :
Author : Paul S. Braterman
Publisher :
Page : 428 pages
File Size : 26,25 MB
Release : 1989-02
Category :
ISBN : 9781461307563
Author : Alexander D. Garnovskii
Publisher : CRC Press
Page : 568 pages
File Size : 28,38 MB
Release : 2003-04-25
Category : Science
ISBN : 1135542376
This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
Author : Geoffrey Wilkinson
Publisher : Pergamon
Page : 638 pages
File Size : 27,57 MB
Release : 1987
Category : Science
ISBN :
Author : Victor Gutmann
Publisher : Springer Science & Business Media
Page : 181 pages
File Size : 10,24 MB
Release : 2012-12-06
Category : Science
ISBN : 3709181941
Considerable attention has been focussed on non-aqueous chemistry in the last decade and this situation has arisen no doubt from a realization of the vast application of this branch of chemistry. Within this field much energetic work has been channelled into the determination of the coordination chemistry of tran sition metals in these solvent 8ystems. Elaborate experimental techniques have been developed to discover, in particular, the magnetic and spectral properties of complex compounds, and the theoretical background of such systems has been expanded to corroborate, as far as possible, the experimental results. This text has, however, a different bias from many books currently available on this branch of chemistry, and is designed to be a survey of known facts on many of the non-aqueous solvents currently in use mainly in the field of halogen chemistry, together with a discussion of these facts in the light of accepted principles. As such, it is hoped to close a gap in the literature of which many workers and advanced students in this field will be aware. The treatment is meant to be selective rather than completely comprehensive and must unevitably reflect some of the special interests of the author.
Author : G. J. Leigh
Publisher : Royal Society of Chemistry
Page : 416 pages
File Size : 45,80 MB
Release : 2002
Category : Science
ISBN : 0854044698
Joseph Chatt was a pioneering figure in coordination chemistry. Intended as a record of Chatt's life, work, and influence, this book begins with a description of Chatt's career presented by co-workers, contemporaries, and students, then goes on to show that many of today's leading practitioners in the field have been influenced by Chatt. The latest research in coordination chemistry is presented to highlight Chatt's continuing legacy, in sections on the synthesis and reactivity of hydrido and dihydrogen complexes, the chemistry of phosphines, transition metal complexes of olefins and related isolobal ligands, chemistry related to dinitrogen complexes, the biological work of the ARC unit of nitrogen fixation at the University of Sussex, and patterns and generalizations in stability and reactivity. Leigh is affiliated with the University of Sussex, UK, and Winterton is affiliated with the University of Liverpool, UK. The book is distributed in the US by Springer Verlag. Annotation copyrighted by Book News Inc., Portland, OR.
Author : Shinichi Kawaguchi
Publisher : Springer
Page : 123 pages
File Size : 35,67 MB
Release : 2012-05-06
Category : Science
ISBN : 9783642501494
Metal complexes play important roles as catalysts or other participants in synthetic and biological reactions. Substrates and sometimes attacking reagents also are activated through coordination with metal atoms or ions. In these events the natures not only of the central metals but also of ancillary ligands exert important influences on the stability and reactivity of the coordinated substrates. A ligand in general can adopt various coordination modes depending on its chemical environment, thus functioning as a probe. The number of coordination modes increases with increasing complexity of the ligand. In this book it is shown that even the simplest mono- and diatomic ligands such as H, CO, and N2 exhibit a variety of coordination modes, which are related to their reactions. The thiocyanate anion is taken up as a representative of the triatomic ambidentate ligands, and factors influencing the preferences for N- und S-bonding are summarized. Coordination chemistry of ß-dicarbonyl compounds is a highlight of this book. Acetylacetone, one of the most familiar Werner ligands, is shown to favor -carbon and n-allylic bonding in many instances. Its versatile behaviour in changing coordination modes is revealed.
Author : Chandraleka Saravanan
Publisher : BoD – Books on Demand
Page : 122 pages
File Size : 23,26 MB
Release : 2018-05-23
Category : Science
ISBN : 1789231825
The book Ligand describes the diversity and versatility of ligands, covering structural features, donor-acceptor properties and secondary functions like molecular recognition. Moreover, this book also provides a comprehensive account on the applicability like catalysis, sensors, supramolecular assembly, photochemical property, bioinorganic chemistry, and so on. The advancement of fundamentals in ligand design and the control of physicochemical properties of coordination compounds has largely increased emphasis on understanding the structural and electronic features toward different perspectives in materials science. In this regard, this book has a special appeal to chemists, biologists and others. This book will be beneficial for the graduate students, teachers, researchers and other professionals who are interested to fortify and expand their knowledge in chemistry, biology, microbiology, biotechnology, materials science, environmental science and so on.
Author :
Publisher :
Page : pages
File Size : 47,75 MB
Release : 1987
Category : Coordination compounds
ISBN : 9780080262321