The Entropy Principle


Book Description

Entropy – the key concept of thermodynamics, clearly explained and carefully illustrated. This book presents an accurate definition of entropy in classical thermodynamics which does not “put the cart before the horse” and is suitable for basic and advanced university courses in thermodynamics. Entropy is the most important and at the same time the most difficult term of thermodynamics to understand. Many students are discontent with its classical definition since it is either based on “temperature” and “heat” which both cannot be accurately defined without entropy, or since it includes concepts such as “molecular disorder” which does not fit in a macroscopic theory. The physicists Elliott Lieb and Jakob Yngvason have recently developed a new formulation of thermodynamics which is free of these problems. The Lieb-Yngvason formulation of classical thermodynamics is based on the concept of adiabatic accessibility and culminates in the entropy principle. The entropy principle represents the accurate mathematical formulation of the second law of thermodynamics. Temperature becomes a derived quantity whereas ”heat” is no longer needed. This book makes the Lieb-Yngvason theory accessible to students. The presentation is supplemented by seven illustrative examples which explain the application of entropy and the entropy principle in practical problems in science and engineering.




Entropy Measures, Maximum Entropy Principle and Emerging Applications


Book Description

The last two decades have witnessed an enormous growth with regard to ap plications of information theoretic framework in areas of physical, biological, engineering and even social sciences. In particular, growth has been spectac ular in the field of information technology,soft computing,nonlinear systems and molecular biology. Claude Shannon in 1948 laid the foundation of the field of information theory in the context of communication theory. It is in deed remarkable that his framework is as relevant today as was when he 1 proposed it. Shannon died on Feb 24, 2001. Arun Netravali observes "As if assuming that inexpensive, high-speed processing would come to pass, Shan non figured out the upper limits on communication rates. First in telephone channels, then in optical communications, and now in wireless, Shannon has had the utmost value in defining the engineering limits we face". Shannon introduced the concept of entropy. The notable feature of the entropy frame work is that it enables quantification of uncertainty present in a system. In many realistic situations one is confronted only with partial or incomplete information in the form of moment, or bounds on these values etc. ; and it is then required to construct a probabilistic model from this partial information. In such situations, the principle of maximum entropy provides a rational ba sis for constructing a probabilistic model. It is thus necessary and important to keep track of advances in the applications of maximum entropy principle to ever expanding areas of knowledge.




Entropy Principle for the Development of Complex Biotic Systems


Book Description

The concept of entropy in thermodynamics is a complex one, though it is fundamental in understanding physics, the workings of the mind, and biology. Entropy is the measure of the quality of energy, and it can also refer to the turn from order to disorder or randomness in isolated systems. In open systems, such as biology, entropy is formulated in terms of production and energy flow. This book establishes a novel view of complex biological systems and the earth using this concept of entropy, encompassing the interdisciplinary area of biology, ecology and physics. This book considers the development over time of a range of biologically complex systems such as plants, animals, humans, and ecosystems, describing them in terms of the second law of thermodynamics, entropy. With its broad coverage of biological systems, this book will be useful for students of environmental science as well as students in biology and physics. - Includes discussion of multiple complex systems including the earth and biological systems within it. - Suitable for those with little physics background who wish to learn how the laws of physics apply to ecological systems. - Clearly organized by system, making information easy to access.




A Treatise of Heat and Energy


Book Description

This textbook explains the meaning of heat and work and the definition of energy and energy systems. It describes the constructive role of entropy growth and makes the case that energy matters, but entropy growth matters more. Readers will learn that heat can be transferred, produced, and extracted, and that the understanding of generalized heat extraction will revolutionize the design of future buildings as thermal systems for managing low grade heat and greatly contribute to enhanced efficiency of tomorrow’s energy systems and energy ecosystems. Professor Wang presents a coherent theory-structure of thermodynamics and clarifies the meaning of heat and the definition of energy in a manner that is both scientifically rigorous and engaging, and explains contemporary understanding of engineering thermodynamics in continuum of its historical evolution. The textbook reinforces students’ grasp of concepts with end-of-chapter problems and provides a historical background of pioneering work by Black, Laplace, Carnot, Joule, Thomson, Clausius, Maxwell, Planck, Gibbs, Poincare and Prigogine. Developed primarily as a core text for graduate students in engineering programs, and as reference for professional engineers, this book maximizes readers’ understanding and shines a light on new horizons for our energy future.




Maximum Entropy and Ecology


Book Description

This pioneering graduate textbook provides readers with the concepts and practical tools required to understand the maximum entropy principle, and apply it to an understanding of ecological patterns. Rather than building and combining mechanistic models of ecosystems, the approach is grounded in information theory and the logic of inference. Paralleling the derivation of thermodynamics from the maximum entropy principle, the state variable theory of ecology developed in this book predicts realistic forms for all metrics of ecology that describe patterns in the distribution, abundance, and energetics of species over multiple spatial scales, a wide range of habitats, and diverse taxonomic groups. The first part of the book is foundational, discussing the nature of theory, the relationship of ecology to other sciences, and the concept of the logic of inference. Subsequent sections present the fundamentals of macroecology and of maximum information entropy, starting from first principles. The core of the book integrates these fundamental principles, leading to the derivation and testing of the predictions of the maximum entropy theory of ecology (METE). A final section broadens the book's perspective by showing how METE can help clarify several major issues in conservation biology, placing it in context with other theories and highlighting avenues for future research.




Beyond the Second Law


Book Description

The Second Law, a cornerstone of thermodynamics, governs the average direction of dissipative, non-equilibrium processes. But it says nothing about their actual rates or the probability of fluctuations about the average. This interdisciplinary book, written and peer-reviewed by international experts, presents recent advances in the search for new non-equilibrium principles beyond the Second Law, and their applications to a wide range of systems across physics, chemistry and biology. Beyond The Second Law brings together traditionally isolated areas of non-equilibrium research and highlights potentially fruitful connections between them, with entropy production playing the unifying role. Key theoretical concepts include the Maximum Entropy Production principle, the Fluctuation Theorem, and the Maximum Entropy method of statistical inference. Applications of these principles are illustrated in such diverse fields as climatology, cosmology, crystal growth morphology, Earth system science, environmental physics, evolutionary biology and technology, fluid turbulence, microbial biogeochemistry, plasma physics, and radiative transport, using a wide variety of analytical and experimental techniques. Beyond The Second Law will appeal to students and researchers wishing to gain an understanding of entropy production and its central place in the science of non-equilibrium systems – both in detail and in terms of the bigger picture.




Entropy Theory and its Application in Environmental and Water Engineering


Book Description

Entropy Theory and its Application in Environmental and Water Engineering responds to the need for a book that deals with basic concepts of entropy theory from a hydrologic and water engineering perspective and then for a book that deals with applications of these concepts to a range of water engineering problems. The range of applications of entropy is constantly expanding and new areas finding a use for the theory are continually emerging. The applications of concepts and techniques vary across different subject areas and this book aims to relate them directly to practical problems of environmental and water engineering. The book presents and explains the Principle of Maximum Entropy (POME) and the Principle of Minimum Cross Entropy (POMCE) and their applications to different types of probability distributions. Spatial and inverse spatial entropy are important for urban planning and are presented with clarity. Maximum entropy spectral analysis and minimum cross entropy spectral analysis are powerful techniques for addressing a variety of problems faced by environmental and water scientists and engineers and are described here with illustrative examples. Giving a thorough introduction to the use of entropy to measure the unpredictability in environmental and water systems this book will add an essential statistical method to the toolkit of postgraduates, researchers and academic hydrologists, water resource managers, environmental scientists and engineers. It will also offer a valuable resource for professionals in the same areas, governmental organizations, private companies as well as students in earth sciences, civil and agricultural engineering, and agricultural and rangeland sciences. This book: Provides a thorough introduction to entropy for beginners and more experienced users Uses numerous examples to illustrate the applications of the theoretical principles Allows the reader to apply entropy theory to the solution of practical problems Assumes minimal existing mathematical knowledge Discusses the theory and its various aspects in both univariate and bivariate cases Covers newly expanding areas including neural networks from an entropy perspective and future developments.




The Maximum Entropy Method


Book Description

Forty years ago, in 1957, the Principle of Maximum Entropy was first intro duced by Jaynes into the field of statistical mechanics. Since that seminal publication, this principle has been adopted in many areas of science and technology beyond its initial application. It is now found in spectral analysis, image restoration and a number of branches ofmathematics and physics, and has become better known as the Maximum Entropy Method (MEM). Today MEM is a powerful means to deal with ill-posed problems, and much research work is devoted to it. My own research in the area ofMEM started in 1980, when I was a grad uate student in the Department of Electrical Engineering at the University of Sydney, Australia. This research work was the basis of my Ph.D. the sis, The Maximum Entropy Method and Its Application in Radio Astronomy, completed in 1985. As well as continuing my research in MEM after graduation, I taught a course of the same name at the Graduate School, Chinese Academy of Sciences, Beijingfrom 1987to 1990. Delivering the course was theimpetus for developing a structured approach to the understanding of MEM and writing hundreds of pages of lecture notes.




Entropy Optimization Principles with Applications


Book Description

This senior-level textbook on entropy provides a conceptual framework for the study of probabilistic systems with its elucidation of three key concepts - Shannon's information theory, Jaynes' maximum entropy principle and Kullback's minimum cross-entropy principle.




Entropy Theory in Hydraulic Engineering


Book Description

Vijay Singh explains the basic concepts of entropy theory from a hydraulic perspective and demonstrates the theory's application in solving practical engineering problems.