Fundamentals of Gas-Surface Interactions


Book Description

Fundamentals of Gas–Surface Interactions presents the study of the surface itself and the study of the gas phase partner of the interaction in which physical or chemical transformation of the gas resulted from that interaction. This book discusses the study of the energy and momentum exchanges resulting from the gas–solid physical interaction in which either gas or solid phase properties can be measured. Organized into three parts encompassing 33 chapters, this book begins with an overview of the different sensitive physical methods for the study of surface topography, surface defects, and surface irregularities to an accuracy of a few Angstroms. This text then reviews the adsorption at very low coverage that has yielded to equilibrium analysis. Other chapters consider the measurement of surface area by adsorption and optical techniques. The final chapter deals with scattering processes including momentum and energy transfer. This book is a valuable resource for engineers.







Interactions of Activated Gases with Solids


Book Description

In investigations of the adsorption of nitrogen on solid surfaces, it was shown that when nitrogen molecules are either bombarded by electrons or when they encounter an incandescent metal surface, atoms of nitrogen may be produced which sorb much more readily than the parent molecule. Thus the activated state was shown to be atomic. Burial of argon ions in nickel was studied. It was learned that the sticking probability for these ions depends upon whether the nickel surface is in a cold-worked or an annealed condition (highest sticking probability in the case of cold-worked nickel). This suggests that either grain boundaries or dislocations may provide sites for adsorption but neither possibility can yet be eliminated. Desorption by photons, electrons and ions was observed. Photon and electron bombardment desorption studies demonstrated that desorption occurs by way of an intermediate activated surface state while ion bombardment desorption was observed only as a secondary process in ion burial studies. Desorption by thermal means permitted the determination of energy with which ions are bound in the metal. (Author).




Interaction of Gases with Surfaces


Book Description

Interface phenomena are most fascinating because of the mixing of different scales and the interference of diverse physical processes. This makes it necessary to use different levels of description: microscopic, kinetic, and gas-dynamical. A unified quasiclassical approach is used to answer practical questions dealing with inelastic gas-surface scattering, the kinetics of adsorption layers, the evolution of inhomogeneities and defects at the surface, the Knudsen layer, the development of boundary conditions on the kinetic and gas-dynamical levels, the determination of exchange and slip coefficients, and so on.










Catalog of Technical Reports


Book Description







Exoemission from Processed Solid Surfaces and Gas Adsorption


Book Description

This book focuses on surface activity of electron emission (EE). Prior to protective painting, a steel surface is usually grit blasted or sandblasted to remove scale and contaminants and to roughen the surface. This book emphasizes that such surface treatment causes EE, increasing the strength of paint adhesion. Introduced here are the experimental results of thermally assisted photoelectron emission (TAPE) and tribo-stimulated (rubbing) electron emission (TriboEE) from practical metals after different kinds of surface-treatment processes. A detailed description is given of how Arrhenius activation energies relating to electron transfer through the surface overlayer and also the energy levels of electrons trapped in the overlayer can be obtained, and how TAPE and TriboEE data can be influenced by the chemical properties of that overlayer. This book is composed of four parts: I. Surface treatment processes; II. The principle of EE analysis used for practical surfaces; III. Materials and methods of EE and X-ray photoelectron spectroscopy (XPS); IV. EE and XPS characteristics of practical surfaces. In the last part, the EE and XPS results for metals, semiconductors, and carbon materials are drawn from the author’s own publications. The book will be useful for researchers engaging in surface-treatment processes of various materials.