The kinetics of some unimolecular isomerization reactions in solution and in the gas phase
Author : Derek Charles Montague
Publisher :
Page : pages
File Size : 23,70 MB
Release : 1967
Category :
ISBN :
Author : Derek Charles Montague
Publisher :
Page : pages
File Size : 23,70 MB
Release : 1967
Category :
ISBN :
Author : I. M. Pidgeon
Publisher :
Page : pages
File Size : 37,38 MB
Release : 1985
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Author : Allan Douglas Clements
Publisher :
Page : pages
File Size : 35,3 MB
Release : 1977
Category :
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Author : V.N. Kondratiev
Publisher : Springer Science & Business Media
Page : 254 pages
File Size : 49,41 MB
Release : 2012-12-06
Category : Science
ISBN : 3642676081
The present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.
Author : Barry Woodfine
Publisher :
Page : pages
File Size : 29,46 MB
Release : 1985
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Author : R.G. Compton
Publisher : Elsevier
Page : 797 pages
File Size : 41,10 MB
Release : 1971-01-01
Category : Science
ISBN : 0080868002
Decomposition and Isomerization of Organic Compounds
Author : C. A. Trapp
Publisher : Macmillan
Page : 1008 pages
File Size : 10,19 MB
Release : 2009-12-18
Category : Science
ISBN : 1429231289
With its modern emphasis on the molecular view of physical chemistry, its wealth of contemporary applications, vivid full-color presentation, and dynamic new media tools, the thoroughly revised new edition is again the most modern, most effective full-length textbook available for the physical chemistry classroom. Available in Split Volumes For maximum flexibility in your physical chemistry course, this text is now offered as a traditional text or in two volumes. Volume 1: Thermodynamics and Kinetics; ISBN 1-4292-3127-0 Volume 2: Quantum Chemistry, Spectroscopy, and Statistical Thermodynamics; ISBN 1-4292-3126-2
Author : Niels E. Henriksen
Publisher : Oxford University Press, USA
Page : 391 pages
File Size : 20,14 MB
Release : 2008
Category : Science
ISBN : 0199203865
This book deals with a central topic at the interface of chemistry and physics - the understanding of how the transformation of matter takes place at the atomic level. Building on the laws of physics, the book focuses on the theoretical framework for predicting the outcome of chemical reactions. The style is highly systematic with attention to basic concepts and clarity of presentation. Molecular reaction dynamics is about the detailed atomic-level description of chemical reactions. Based on quantum mechanics and statistical mechanics or, as an approximation, classical mechanics, the dynamics of uni- and bi-molecular elementary reactions are described. The book features a detailed presentation of transition-state theory which plays an important role in practice, and a comprehensive discussion of basic theories of reaction dynamics in condensed phases. Examples and end-of-chapter problems are included in order to illustrate the theory and its connection to chemical problems.
Author : Richard Graham Hopkins
Publisher :
Page : pages
File Size : 46,57 MB
Release : 1971
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Author : Niels Engholm Henriksen
Publisher :
Page : 458 pages
File Size : 20,56 MB
Release : 2019
Category : Science
ISBN : 0198805012
This book describes how chemical reactions take place at the atomic level and how one can calculate the rate of such reactions. The book features a systematic and comprehensive presentation of the subject with a wide range of examples and end-of-chapter problems.