Book Description

Thermodynamic and Transport Properties of Organic Salts is concerned with the thermodynamic and transport properties of organic salts, namely, pure salts, mixtures, and solutions. The transport properties of pure molten salts and binary mixtures of molten salts with organic ions are given, along with the transport properties of organic salts in aqueous solutions. This book is divided into three sections and opens with a discussion on the statistical treatment and of computer simulation methods for molten salts as well as their results for pressure-volume-temperature (PVT) data. The PVT data for organic molten salts determined experimentally are considered, and the thermal properties as well as the melting mechanism of pure salts are described. A method by which PVT data at high pressure can be estimated from those at low pressure with sufficiently high accuracy is also outlined. The next section deals with salt mixtures, their phase diagrams, and their transport properties. The final section looks at the transport properties of organic salts in aqueous solutions; thermodynamic quantities of micelle formation; and formation of lyotropic liquid crystals by organic salts. Two appendixes showing the structure of the pure solids and the use of the melts in electrochemical studies are included. This monograph will be a useful resource for organic chemists.