Titania Carbon Nanotube Composites for Enhanced Photocatalysis


Book Description

ABSTRACT: Photocatalytic composites have been used for the past few decades in a wide range of applications. The most common application is the purification of air and water by removing toxic compounds. There is limited use however towards biocidal applications. Despite their high efficiency, photocatalytic materials are not comparable to the effectiveness of conventional biocidal compounds such as chlorine and alcoholic disinfectants. On the other hand, nearly a decade ago with the discovery of the carbon nanotubes a new vibrant scientific field emerged. Nanotubes are unique structures of carbon that posse amazing electrical, mechanical and thermal properties. In this research carbon nanotubes are used as photocatalyitic enhancers. They were coated with anatase titania to form a composite material. Two different types of nanotubes (metallic versus non-metallic) were used and the photocatalytic activity was measured. The metallic tubes demonstrated exceptional photocatalyitic properties, while non-metallic tubes had low photocatalytic efficiency. The reason for that difference was investigated and was the ma jor focus of this research. The research concluded that the reasons for the high efficiency of the carbon nanotubes were (i) the metallic nature of the tubes and (ii) the possible bond between the titania coating and the underlying graphite layers (C-O-Ti). Since both composites had the same indications regarding the C-O-Ti bond, the metallic nature of the carbon nanotubes is believed to be the most dominant factor contributing to the enhancement of the photocatalysis. The composite material may have other potential applications such as for sensing and photovoltaic uses.




Nanosized Titania Composites for Reinforcement of Photocatalysis and Photoelectrocatalysis


Book Description

This book discusses recent advances in the photocatalytic and electrophotocatalytic applications of titanium dioxide nanocomposites containing polymers and other components. These materials possess photocatalytic, virucidal and antimicrobial efficacy and water and air cleaning abilities against eco-toxicants, and allow water splitting for the generation of chemical fuels. The book considers the ability of nanocomposites’ components to reinforce titania functionality in photocatalysis and photoelectrocatalysis, and presents an overview of their occurrence in nature, their thermodynamic properties, and their toxicity. The volume will be of interest to chemists and material science specialists and practitioners, as well as any reader interested in the recent scientific achievements for green and sustainable development.




Carbon Nanotubes


Book Description

This new book discusses a selection of advanced topics on carbon nanotubes—their extraordinary properties, structure, design, fabrication, development, engineering, functionalization, carbon nanotube enabled nanocomposites, characterization, and, moreover, their utility in many applications. The volume highlights the amazing potential of advanced CNT composites in automotive, aeronautics, spacecrafts, transistors replacing Si electronics, energy, purification, hydrogen storage, tissue regeneration, electrochemical supercapacitors, sensing, biomedical applications, agriculture, energy, and technical applications. The book specifically discusses the applications of carbon nanotubes for a greener environment, as well as applications for biomedical uses, in drug delivery, and in display technology. It also explores the uses of CNTs in the energy and aerospace industries, such as for solar energy conversion, as a lubricant additive for enhancing energy efficiency, and more. Other chapters explore the potential of carbon nanotubes in hydrogen storage and carbon nanotube electronics.




Handbook of Nanomaterials Properties


Book Description

Nanomaterials attract tremendous attention in recent researches. Although extensive research has been done in this field it still lacks a comprehensive reference work that presents data on properties of different Nanomaterials. This Handbook of Nanomaterials Properties will be the first single reference work that brings together the various properties with wide breadth and scope.




Titanium Dioxide Photocatalysis


Book Description

Although the seminal work of Fujishima et al. dates back to 1971, TiO2 still remains the most diffused and studied semiconductor, employed in photo-oxidation processes for cleantech (i.e., polluted water and air treatment), in solar fuel production (mainly hydrogen production by water photo splitting), and in Carbon Capture and Utilization (CCU) processes by CO2 photoreduction. The eleven articles, among them three reviews, in this book cover recent results and research trends of various aspects of titanium dioxide photocatalysis, with the chief aim of improving the final efficiency of TiO2-based materials. Strategies include doping, metal co-catalyst deposition, and the realization of composites with plasmonic materials, other semiconductors, and graphene. Photocatalysts with high efficiency and selectivity can be also obtained by controlling the precise crystal shape (and homogeneous size) and the organization in superstructures from ultrathin films to hierarchical nanostructures. Finally, the theoretical modeling of TiO2 nanoparticles is discussed and highlighted. The range of topics addressed in this book will stimulate the reader’s interest as well as provide a valuable source of information for researchers in academia and industry.




Carbon Nanotubes and Nanoparticles


Book Description

This new volume looks at significant new research, methodologies, and applications in the fields of carbon nanotubes and nanoparticles. It explores a variety of new developments in advanced carbon nanotubes and nanoparticles along with the tools to characterize and predict their properties and behavior. It introduces and reviews methods that are most frequently encountered in sophisticated nano-scaled materials domains, and helps to bridge the gap between classical analysis and modern real-life applications. A diverse array of topics in the field is addressed that provides many practical insights into nanocomposites and nanomaterials sciences.




Carbon Composites


Book Description

This volume demonstrates the unique place in nanotechnology and nanoscience that carbon nanomaterials occupy owing to their exceptional chemical, mechanical, thermal, and electrical properties. Carbon nanomaterials have diverse applications in super strong composite materials, smart sensors, energy storage and conversion, super-capacitors, and more. Focusing on materials rather than mechanics, this volume discusses the key roles of materials science and engineering in the development of composite materials. The result of research by many highly qualified experts in the field of experimental and theoretical research on graphene and its derivatives, the volume describes experimental methods for obtaining and characterizing samples of chemically modified graphene. It reviews the potential application areas and modifications of graphene-based composite materials and interprets the interesting physical effects discovered for the first time for graphene materials under consideration. This book covers the innovative methodologies and strategies adopted in carbon materials research area including: Synthesis, characterization, and functionalization of carbon nanotubes and graphene Surface modification of graphene Carbon-based nanostructured materials The use of carbon nanomaterials for energy applications Development of carbon nanotubes reinforced metal matrix composites and non-metallic composites and their myriad potential end-use applications Key challenges to the successful and widespread implementation of carbon nanotubes reinforced metal matrix composites and non-metallic composites Methods for quantification and improved control of carbon nanotubes distributions Recent research and design trends for carbon nanomaterials-based sensors for a variety of applications Advances and potential applications in environmental monitoring and healthcare The book will be useful for postgraduate students and researchers as well as for experts in industrial sectors. It will also appeal to those involved in materials science and nanotechnology.




Carbon Nanotube Based Composites


Book Description

Carbon nanotubes (CNTs) have amazing properties and a key way to take advantage of this is by incorporating nanotubes into a matrix to build composite materials. The best candidates for this task are undoubtedly polymers. Almost every characteristic of a polymer can be significantly enhanced by adding carbon nanotubes and as a result, new potential applications of carbon nanotube enhanced polymer composites are discovered every day. However, before carbon nanotube enhanced polymer composites become commonplace there are some tough challenges that need to be overcome. This book reviews the status of worldwide research in both single-walled and multi-walled carbon nanotube based composites. It serves as a practical guide on carbon nanotube based composites and a reference to students and researchers from the academia and industry.




Photo-catalytic Control Technologies of Flue Gas Pollutants


Book Description

This book introduces the theory and applications of nanometer photocatalysis, and it briefly presents the concept of photocatalysts, photocatalytic reaction mechanisms and kinetics, and photocatalytic reactor design. In addition, the use of photocatalysis in the control of flue-gas pollutants is discussed in detail. The book also describes how a photocatalytic reactor is designed and implemented to evaluate the photocatalytic oxidation capacity of different photocatalysts on elemental mercury in a simulated flue gas. After that, the effect of photocatalysts on the SO2, NOx and Hg removal in the flue gas is studied. Photocatalytic cleaning technology can be applied not only in gas pollutant cleaning at power plants, but also in wastewater purification. Readers gain a comprehensive understanding of possible mercury emission control methods and the industrial applications of these technologies.




Photochemistry


Book Description

Annotation 'Photochemistry' reviews photo-induced processes that have relevance to the wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology.