Ultrafast Infrared Vibrational Spectroscopy


Book Description

The advent of laser-based sources of ultrafast infrared pulses has extended the study of very fast molecular dynamics to the observation of processes manifested through their effects on the vibrations of molecules. In addition, non-linear infrared spectroscopic techniques make it possible to examine intra- and intermolecular interactions and how such interactions evolve on very fast time scales, but also in some instances on very slow time scales. Ultrafast Infrared Vibrational Spectroscopy is an advanced overview of the field of ultrafast infrared vibrational spectroscopy based on the scientific research of the leading figures in the field. The book discusses experimental and theoretical topics reflecting the latest accomplishments and understanding of ultrafast infrared vibrational spectroscopy. Each chapter provides background, details of methods, and explication of a topic of current research interest. Experimental and theoretical studies cover topics as diverse as the dynamics of water and the dynamics and structure of biological molecules. Methods covered include vibrational echo chemical exchange spectroscopy, IR-Raman spectroscopy, time resolved sum frequency generation, and 2D IR spectroscopy. Edited by a recognized leader in the field and with contributions from top researchers, including experimentalists and theoreticians, this book presents the latest research methods and results. It will serve as an excellent resource for those new to the field, experts in the field, and individuals who want to gain an understanding of particular methods and research topics.




Ultrafast Optics And Spectroscopy In Physical Chemistry


Book Description

The primary goal of this text book is to ensure that any physical science student, even one who has never heard of the subject, should be able to learn what ultrafast spectroscopy is, why optics related to the subject requires special attention, how to use the basic ideas of the subject in laboratory-based ultrafast spectroscopy experiments, how to interpret the experimental observations and so on. This book gives a more than adequate introduction to mathematical representation of an ultrafast pulse, chirp, time-band width product, nonlinear optical effects, dispersion effects, construction of ultrafast laser, ultrafast measurement techniques and different ultrafast processes of chemical interest.




Chemical Applications of Ultrafast Spectroscopy


Book Description

The recent improvements in the techniques for producing very short duration pulses of laser light have allowed chemists to study processes taking place on similarly short timescales, now typically in the range of 10 to 10 seconds. This book describes methods for generating and characterising picosecond pulses, and then provides a discussion of current experimental techniques for the study of ultrafast chemical processes. The applications to specific chemical problems are divided into chapters on the vapour, liquid, and solid phases.




Ultrafast Processes in Spectroscopy


Book Description

This volume is a collection of papers presented at the Ninth International Symposium on "Ultrafast Processes in Spectroscopy" (UPS '95) held at the International Centre for Theo retical Physics (ICTP), Trieste (Italy), October 30 -November 3, 1995. These meetings have become recognized as the major forum in Europe for discussion of new work in this rapidly moving field. The UPS'95 Conference in Trieste brought together a multidisciplinary group of researchers sharing common interests in the generation of ultrashort optical pulses and their application to studies of ultrafast phenomena in physics, chemistry, material science, electronics, and biology. It was attended by approximately 250 participants from 20 countries and the five-day program comprises more than 200 papers. The progress of both technology and applications in the field of ultrafast processes during these last years is truly remarkable. The advent of all solid state femtosecond lasers and the extension of laser wavelengths by frequency conversion techniques provide a large variety of high-performance light sources for ultrashort pulses. With these sources ultrafast phenomena in physical, chemical and biological systems and in electronic de vi(:es are now studied extensively. Ultrafast technology is becoming one of the basic and common tools presently entering a wide variety of scientific fields not only for basic re search but also for promoting new applications in various areas. We feel that these pro ceedings vividly reflect the present status of the field.




Ultrafast Spectroscopy


Book Description

The goal of this book is to provide a simple and conceptually intuitive introduction to nonlinear spectroscopy via the formalism of quantum processes and wavepacket dynamics.




Introduction to Laser Spectroscopy


Book Description

Introduction to Laser Spectroscopy is a well-written, easy-to-read guide to understanding the fundamentals of lasers, experimental methods of modern laser spectroscopy and applications. It provides a solid grounding in the fundamentals of many aspects of laser physics, nonlinear optics, and molecular spectroscopy. In addition, by comprehensively combining theory and experimental techniques it explicates a variety of issues that are essential to understanding broad areas of physical, chemical and biological science. Topics include key laser types - gas, solid state, and semiconductor - as well as the rapidly evolving field of ultrashort laser phenomena for femtochemistry applications. The examples used are well researched and clearly presented. Introduction to Laser Spectroscopy is strongly recommended to newcomers as well as researchers in physics, engineering, chemistry and biology.* A comprehensive course that combines theory and practice* Includes a systematic and comprehensive description for key laser types* Written for students and professionals looking to gain a thorough understanding of modern laser spectroscopy




Femtosecond Laser Spectroscopy


Book Description

The embryonic development of femtoscience stems from advances made in the generation of ultrashort laser pulses. Beginning with mode-locking of glass lasers in the 1960s, the development of dye lasers brought the pulse width down from picoseconds to femtoseconds. The breakthrough in solid state laser pulse generation provided the current reliable table-top laser systems capable of average power of about 1 watt, and peak power density of easily watts per square centimeter, with pulse widths in the range of four to eight femtoseconds. Pulses with peak power density reaching watts per square centimeter have been achieved in laboratory settings and, more recently, pulses of sub-femtosecond duration have been successfully generated. As concepts and methodologies have evolved over the past two decades, the realm of ultrafast science has become vast and exciting and has impacted many areas of chemistry, biology and physics, and other fields such as materials science, electrical engineering, and optical communication. In molecular science the explosive growth of this research is for fundamental reasons. In femtochemistry and femtobiology chemical bonds form and break on the femtosecond time scale, and on this scale of time we can freeze the transition states at configurations never before seen. Even for n- reactive physical changes one is observing the most elementary of molecular processes. On a time scale shorter than the vibrational and rotational periods the ensemble behaves coherently as a single-molecule trajectory.




Spectroscopy for Materials Characterization


Book Description

SPECTROSCOPY FOR MATERIALS CHARACTERIZATION Learn foundational and advanced spectroscopy techniques from leading researchers in physics, chemistry, surface science, and nanoscience In Spectroscopy for Materials Characterization, accomplished researcher Simonpietro Agnello delivers a practical and accessible compilation of various spectroscopy techniques taught and used to today. The book offers a wide-ranging approach taught by leading researchers working in physics, chemistry, surface science, and nanoscience. It is ideal for both new students and advanced researchers studying and working with spectroscopy. Topics such as confocal and two photon spectroscopy, as well as infrared absorption and Raman and micro-Raman spectroscopy, are discussed, as are thermally stimulated luminescence and spectroscopic studies of radiation effects on optical materials. Each chapter includes a basic introduction to the theory necessary to understand a specific technique, details about the characteristic instrumental features and apparatuses used, including tips for the appropriate arrangement of a typical experiment, and a reproducible case study that shows the discussed techniques used in a real laboratory. Readers will benefit from the inclusion of: Complete and practical case studies at the conclusion of each chapter to highlight the concepts and techniques discussed in the material Citations of additional resources ideal for further study A thorough introduction to the basic aspects of radiation matter interaction in the visible-ultraviolet range and the fundamentals of absorption and emission A rigorous exploration of time resolved spectroscopy at the nanosecond and femtosecond intervals Perfect for Master and Ph.D. students and researchers in physics, chemistry, engineering, and biology, Spectroscopy for Materials Characterization will also earn a place in the libraries of materials science researchers and students seeking a one-stop reference to basic and advanced spectroscopy techniques.




Ultrafast Optics


Book Description

A comprehensive treatment of ultrafast optics This book fills the need for a thorough and detailed account of ultrafast optics. Written by one of the most preeminent researchers in the field, it sheds new light on technology that has already had a revolutionary impact on precision frequency metrology, high-speed electrical testing, biomedical imaging, and in revealing the initial steps in chemical reactions. Ultrafast Optics begins with a summary of ultrashort laser pulses and their practical applications in a range of real-world settings. Next, it reviews important background material, including an introduction to Fourier series and Fourier transforms, and goes on to cover: Principles of mode-locking Ultrafast pulse measurement methods Dispersion and dispersion compensation Ultrafast nonlinear optics: second order Ultrafast nonlinear optics: third order Mode-locking: selected advanced topics Manipulation of ultrashort pulses Ultrafast time-resolved spectroscopy Terahertz time-domain electromagnetics Professor Weiner's expertise and cutting-edge research result in a book that is destined to become a seminal text for engineers, researchers, and graduate students alike.




Ultrafast Phenomena in Molecular Sciences


Book Description

This book presents the latest developments in Femtosecond Chemistry and Physics for the study of ultrafast photo-induced molecular processes. Molecular systems, from the simplest H2 molecule to polymers or biological macromolecules, constitute central objects of interest for Physics, Chemistry and Biology, and despite the broad range of phenomena that they exhibit, they share some common behaviors. One of the most significant of those is that many of the processes involving chemical transformation (nuclear reorganization, bond breaking, bond making) take place in an extraordinarily short time, in or around the femtosecond temporal scale (1 fs = 10-15 s). A number of experimental approaches - very particularly the developments in the generation and manipulation of ultrashort laser pulses - coupled with theoretical progress, provide the ultrafast scientist with powerful tools to understand matter and its interaction with light, at this spatial and temporal scale. This book is an attempt to reunite some of the state-of-the-art research that is being carried out in the field of ultrafast molecular science, from theoretical developments, through new phenomena induced by intense laser fields, to the latest techniques applied to the study of molecular dynamics.