Environmental Barrier Coatings


Book Description

The global increase in air travel will require commercial vehicles to be more efficient than ever before. Advanced engine hot section materials are a key technology required to keep fuel consumption and emission to a minimum in next-generation gas turbines. Ceramic matrix composites (CMCs) are the most promising material to revolutionize gas turbine hot section materials technology because of their excellent high‐temperature properties. Rapid surface recession due to volatilization by water vapor is the Achilles heel of CMCs. Environmental barrier coatings (EBCs) is an enabling technology for CMCs, since it protects CMCs from water vapor. The first CMC component entered into service in 2016 in a commercial engine, and more CMC components are scheduled to follow within the next few years. One of the most difficult challenges to CMC components is EBC durability, because failure of EBC leads to a rapid reduction in CMC component life. Key contributors to EBC failure include recession, oxidation, degradation by calcium‐aluminum‐magnesium silicates (CMAS) deposits, thermal and thermo‐mechanical strains, particle erosion, and foreign object damage (FOD). Novel EBC chemistries, creative EBC designs, and robust processes are required to meet EBC durability challenges. Engine-relevant testing, characterization, and lifing methods need to be developed to improve EBC reliability. The aim of this Special Issue is to present recent advances in EBC technology to address these issues. In particular, topics of interest include but are not limited to the following: • Novel EBC chemistries and designs; • Processing including plasma spray, suspension plasma spray, solution precursor plasma spray, slurry process, PS-PVD, EB-PVD, and CVD; • Testing, characterization, and modeling; • Lifing.




Ceramic Coatings for High-Temperature Environments


Book Description

This book addresses the recent trends in thermal and environmental barrier coatings and their applications in extreme environments. It introduces the state of the art in coating materials and processes for high and ultrahigh-temperature environments and identifies areas for improvement in materials selection, performance upgrades, design considerations, and manufacturing methods. This book also covers fundamental studies involving modelling, creating coating architectures, coating preparation methods, and coating capability throughout a wide temperature range. The book examines a variety of high-temperature coatings prepared through various synthesis processes such as thermal spraying, electron beam evaporation, and sol–gel methods. This book also covers ultrahigh-temperature ceramic (UHTC) materials and provides a brief overview of the synthesis method, densification processes, and coating methods along with the properties and applications of emerging high entropy UHTCs. With contributions from international researchers active in the field, this edited book features the most recent and up-to-date literature references for a broad readership consisting of academic and industrial professionals. It is suitable for graduate students as well as materials scientists and engineers working in the area of high and ultrahigh-temperature ceramic materials.




Advanced Ceramic Coatings and Interfaces


Book Description

Recent advances in coating development, processing, microstructure and property characterization, and life prediction are included in this book, which came from the proceedings of the 30th International Conference on Advanced Ceramics and Composites, January 22-27, 2006, Cocoa Beach, Florida. Organized and sponsored by The American Ceramic Society and The American Ceramic Society's Engineering Ceramics Division in conjunction with the Nuclear and Environmental Technology Division.. Integrated structural, environmental properties and functionality through advanced coating processing and structural design are emphasized in this book.




Advances in High Temperature Ceramic Matrix Composites and Materials for Sustainable Development


Book Description

Global population growth and tremendous economic development has brought us to the crossroads of long-term sustainability and risk of irreversible changes in the ecosystem. Energy efficient and ecofriendly technologies and systems are critically needed for further growth and sustainable development. While ceramic matrix composites were originally developed to overcome problems associated with the brittle nature of monolithic ceramics, today the composites can be tailored for customized purposes and offer energy efficient and ecofriendly applications, including aerospace, ground transportation, and power generation systems. The 9th International Conference on High Temperature Ceramic Matrix Composites (HTCMC 9) was held in Toronto, Canada, June 26-30, 2016 to discuss challenges and opportunities in manufacturing, commercialization, and applications for these important material systems. The Global Forum on Advanced Materials and Technologies for Sustainable Development (GFMAT 2016) was held in conjunction with HTCMC 9 to address key issues, challenges, and opportunities in a variety of advanced materials and technologies that are critically needed for sustainable societal development. This Ceramic Transactions volume contains a collection of peer reviewed papers from the 16 below symposia that were submitted from these two conferences Design and Development of Advanced Ceramic Fibers, Interfaces, and Interphases in Composites- A Symposium in Honor of Professor Roger Naslain Innovative Design, Advanced Processing, and Manufacturing Technologies Materials for Extreme Environments: Ultrahigh Temperature Ceramics (UHTCs) and Nano-laminated Ternary Carbides and Nitrides (MAX Phases) Polymer Derived Ceramics and Composites Advanced Thermal and Environmental Barrier Coatings: Processing, Properties, and Applications Thermomechanical Behavior and Performance of Composites Ceramic Integration and Additive Manufacturing Technologies Component Testing and Evaluation of Composites CMC Applications in Transportation and Industrial Systems Powder Processing Innovation and Technologies for Advanced Materials and Sustainable Development Novel, Green, and Strategic Processing and Manufacturing Technologies Ceramics for Sustainable Infrastructure: Geopolymers and Sustainable Composites Advanced Materials, Technologies, and Devices for Electro-optical and Medical Applications Porous Ceramics for Advanced Applications Through Innovative Processing Multifunctional Coatings for Sustainable Energy and Environmental Applications




Future Development of Thermal Spray Coatings


Book Description

Future Development of Thermal Spray Coatings discusses the latest developments and research trends in the thermal spray industry. The book presents a timely guide to new applications and techniques. After an introduction to thermal spray coatings by the editor, Part One covers new types and properties of thermal spray coatings. Chapters look at feedstock suspensions and solutions, the application of solution precursor spray techniques to obtain ceramic films and coatings, cold spray techniques and warm spray technology amongst others. Part Two of the book moves on to discuss new applications for thermal spray coatings such as the use of thermal spray coatings in environmental barrier coatings, thermal spray coatings in renewable energy applications and manufacturing engineering in thermal spray technologies by advanced robot systems and process kinematics. - Timely guide on the current advancements and research trends in thermal spray technology - Reviews different types of thermal spray coatings - Presents a wide variety of applications for this emerging technology




In situ generated ß-Yb₂Si₂O₇ environmental barrier coatings to protect non-oxide silicon-based ceramics in gas turbines (Band 16)


Book Description

In face of an accelerating climate change, the reduction and substitution of fossil fuels is crucial to decarbonize energy production. Gas turbines can operate with versatile fuel sources like natural gas and future fuels such as hydrogen and ammonia. In a next future, thermal efficiencies above 65% are expected to be achieved by implementing non-oxide silicon-based (i.e. Si₃N₄, SiC and SiC/SiC) ceramic components. However, water vapor is one of the main combustion products, which leads to rapid corrosion due to the volatilization of the protective SiO₂ layer above 1200 °C. Hence, an in situ generated Yb₂Si₂O₇ double layered environmental barrier coating system composed of silazanes and the active fillers Yb2O3 and Si was processed at 1415 °C for 5 h in air to protect Si3N4, SiC and SiC/SiC from corrosion. The easy to apply coating system exhibits a dense microstructure with a thickness of up to 150 µm, besides an excellent adhesion strength (36.9 ± 6.2 MPa), hardness (6.9 ± 1.6 GPa) and scratch resistance (28 N). It remarkably overcomes over 15 thermal cycles between 1200 and 20 °C and shows almost no mass loss after harsh hot gas corrosion at 1200 °C for 200 h (pH2O = 0.15 atm, v = 100 m s⁻¹).




Protective Thin Coatings Technology


Book Description

Hard or protective coatings are widely used in conventional and modern industries and will continue to play a key role in future manufacturing, especially in the micro and nano areas. Protective Thin Coatings Technology highlights the developments and advances in the preparation, characterization, and applications of protective micro-/nanoscaled films and coatings. This book Covers technologies for sputtering of flexible hard nanocoatings, deposition of solid lubricating films, and multilayer transition metal nitrides Describes integrated nanomechanical characterization of hard coatings, corrosion and tribo-corrosion of hard coatings, and high entropy alloy films and coatings Investigates thin films and coatings for high-temperature applications, nanocomposite coatings on magnesium alloys, and the correlation between coating properties and industrial applications Features various aspects of hard coatings, covering advanced sputtering technologies, structural characterizations, and simulations, as well as applications This first volume in the two-volume set, Protective Thin Coatings and Functional Thin Films Technology, will benefit industry professionals and researchers working in areas related to semiconductors, optoelectronics, plasma technology, solid-state energy storages, and 5G, as well as advanced students studying electrical, mechanical, chemical, and material engineering.




Ceramic Matrix Composites


Book Description

This book is a comprehensive source of information on various aspects of ceramic matrix composites (CMC). It covers ceramic and carbon fibers; the fiber-matrix interface; processing, properties and industrial applications of various CMC systems; architecture, mechanical behavior at room and elevated temperatures, environmental effects and protective coatings, foreign object damage, modeling, life prediction, integration and joining. Each chapter in the book is written by specialists and internationally renowned researchers in the field. This book will provide state-of-the-art information on different aspects of CMCs. The book will be directed to researchers working in industry, academia, and national laboratories with interest and professional competence on CMCs. The book will also be useful to senior year and graduate students pursuing degrees in ceramic science and engineering, materials science and engineering, aeronautical, mechanical, and civil or aerospace engineering. Presents recent advances, new approaches and discusses new issues in the field, such as foreign object damage, life predictions, multiscale modeling based on probabilistic approaches, etc. Caters to the increasing interest in the application of ceramic matrix composites (CMC) materials in areas as diverse as aerospace, transport, energy, nuclear, and environment. CMCs are considered ans enabling technology for advanced aeropropulsion, space propulsion, space power, aerospace vehicles, space structures, as well as nuclear and chemical industries. Offers detailed descriptions of ceramic and carbon fibers; fiber-matrix interface; processing, properties and industrial applications of various CMC systems; architecture, mechanical behavior at room and elevated temperatures, environmental effects and protective coatings, foreign object damage, modeling, life prediction, integration/joining.




Advanced Ceramic Coatings and Interfaces II, Volume 28, Issue 3


Book Description

Papers from The American Ceramic Society's 31st International Conference on Advanced Ceramics and Composites, held in Daytona Beach, Florida, January 21-26, 2007. Focuses on recent advances in coating development, processing, structural design, microstructure and property characterization, and life prediction.