Utilization of Coal Bed Methane Water (CBMW) for Irrigation of Forage, Medicinal and Bio-fuel Crops


Book Description

Coal bed methane is a highly used natural gas extracted from coal seams. Its production has greatly increased in the last 25 years. The U.S. is the top producer of coal bed methane in the entire world, and produced around 41.51 billion m3 in the year 2013. Coal bed methane production also releases large volumes of co-produced water or coal bed methane water (CBMW) to the surface. Due to its chemical properties this water is sometimes considered disadvantageous for soil and environment but if properly managed and used CBMW also have some beneficial effects. There are a number of research studies that show a positive impact of CBMW on crop production especially in Wyoming. Properties of CBMW vary greatly. CBMW produced in Wyoming’s Powder River basin is considered better for irrigation compared to CBMW produce in other states, but still most of the CBMW produced in this area is either re-injected back or discharged to the surface. Using CBMW produced in Wyoming for irrigation of various crops would address the problem of fresh water scarcity, leading to increases in production and also contributing towards beneficial disposal of this water. Hence the objective of this thesis was to conduct field and greenhouse studies on various crops to determine short and long term impact of CBMW on various bio-fuels, forage, and medicinal crops. Three separate research studies were conducted to meet the desired objectives. Two studies were conducted in the greenhouse and one in the field. The first greenhouse study was to determine the effect of different doses of CBMW on plant biomass, essential oil yield and essential oil content of dill and wyoming big sagebrush. Treatments consisted of 0% CBMW (tap water only), 25% CBMW (25% CBMW, 75% tap water), 50% CBMW (50% CBMW, 50% tap water), 75% CBMW (75% CBMW, 25% tap water) and 100% CBMW. The experiment was carried out as completely randomized design with 6 replications. After the study, plant biomass was determined for both crops. Distillation was carried out only for dill as sagebrush did not yield sufficient biomass. Soil sampling was also carried out. Results revealed, plant biomass and essential oil content of dill to be statistically similar in all the treatments, but there were changes seen in some of the constituents of essential oil. For sagebrush fresh plant biomass and plant height was maximum at 0% CBMW treatment and reduced significantly on 25% CBMW treatment, but did not reduced further on 50%, 75% and 100% CBMW treatments. The second greenhouse research was to determine forage yield and quality of oat and alfalfa grown on various concentrations of CBMW. Treatments consisted of different doses of CBMW, as done previously. A similar experimental design was followed. Yield of forages were compared using regression, and forage quality was compared using fisher least significant difference. After the study fresh and dry biomass was determined for both crops. Forage analysis was also carried out for forage quality. Results demonstrated, a gradual decrease (21-33% for alfalfa and 10–16% for oat) in fresh biomass for both crops with increasing concentration of CBMW treatments but their forage quality remained unchanged. A field study was conducted to determine long term possibility of growing wormwood, switchgrass, native spearmint, japanese cornmint, alfalfa, and brome grass receiving CBMW as irrigation. Selected field plots had been receiving CBMW treatment for two consecutive years and similar treatment was applied in the third year. Experimental design was randomized complete block design (split plot in space) with 4 replications and 2 factors (water treatment and crops). Crops were harvested at various times and their fresh and dry weight was determined. Oil crops were distilled and forage quality analysis was carried out for forage crops. Results demonstrated that CBMW did not have any impact on crop biomass, oil yield or forage quality, which was confirmed by p-value from the ANOVA table. The above studies demonstrate the possibility of using CBMW for irrigation of various crops. However, various soil qualities (e.g. pH, electrical conductivity etc.) in both field and greenhouse research were significantly affected by the application of CBMW and therefore need to be considered before application.







Enhancement of Biogenic Coalbed Methane Production and Back Injection of Coalbed Methane Co-Produced Water


Book Description

Biogenic methane is a common constituent in deep subsurface environments such as coalbeds and oil shale beds. Coalbed methane (CBM) makes significant contributions to world natural gas industry and CBM production continues to increase. With increasing CBM production, the production of CBM co-produced water increases, which is an environmental concern. This study investigated the feasibility in re-using CBM co-produced water and other high sodic/saline water to enhance biogenic methane production from coal and other unconventional sources, such as oil shale. Microcosms were established with the selected carbon sources which included coal, oil shale, lignite, peat, and diesel-contaminated soil. Each microcosm contained either CBM coproduced water or groundwater with various enhancement and inhibitor combinations. Results indicated that the addition of nutrients and nutrients with additional carbon can enhance biogenic methane production from coal and oil shale. Methane production from oil shale was much greater than that from coal, which is possibly due to the greater amount of available Dissolved Organic Carbon (DOC) from oil shale. Inconclusive results were observed from the other sources since the incubation period was too low. WRI is continuing studies with biogenic methane production from oil shale.










Coalbed Methane Procduced Water Treatment Using Gas Hydrate Formation at the Wellhead


Book Description

Water associated with coalbed methane (CBM) production is a significant and costly process waste stream, and economic treatment and/or disposal of this water is often the key to successful and profitable CBM development. In the past decade, advances have been made in the treatment of CBM produced water. However, produced water generally must be transported in some fashion to a centralized treatment and/or disposal facility. The cost of transporting this water, whether through the development of a water distribution system or by truck, is often greater than the cost of treatment or disposal. To address this economic issue, BC Technologies (BCT), in collaboration with Oak Ridge National Laboratory (ORNL) and International Petroleum Environmental Consortium (IPEC), proposed developing a mechanical unit that could be used to treat CBM produced water by forming gas hydrates at the wellhead. This process involves creating a gas hydrate, washing it and then disassociating hydrate into water and gas molecules. The application of this technology results in three process streams: purified water, brine, and gas. The purified water can be discharged or reused for a variety of beneficial purposes and the smaller brine can be disposed of using conventional strategies. The overall objectives of this research are to develop a new treatment method for produced water where it could be purified directly at the wellhead, to determine the effectiveness of hydrate formation for the treatment of produced water with proof of concept laboratory experiments, to design a prototype-scale injector and test it in the laboratory under realistic wellhead conditions, and to demonstrate the technology under field conditions. By treating the water on-site, producers could substantially reduce their surface handling costs and economically remove impurities to a quality that would support beneficial use. Batch bench-scale experiments of the hydrate formation process and research conducted at ORNL confirmed the feasibility of the process. However, researchers at BCT were unable to develop equipment suitable for continuous operation and demonstration of the process in the field was not attempted. The significant achievements of the research area: Bench-scale batch results using carbon dioxide indicate>40% of the feed water to the hydrate formation reactor was converted to hydrate in a single pass; The batch results also indicate>23% of the feed water to the hydrate formation reactor (>50% of the hydrate formed) was converted to purified water of a quality suitable for discharge; Continuous discharge and collection of hydrates was achieved at atmospheric pressure. Continuous hydrate formation and collection at atmospheric conditions was the most significant achievement and preliminary economics indicate that if the unit could be made operable, it is potentially economic. However, the inability to continuously separate the hydrate melt fraction left the concept not ready for field demonstration and the project was terminated after Phase Two research.




Assessment of the Environmental Impacts of Coalbed Methane Development in the Powder River Basin - Use of Coalbead Methane Produced Water for Cropland Irrigation


Book Description

Water quality is a major concern with regard to development of coalbed methane (CBM) in the Powder River Basin, Wyoming. Large quantities of water are being produced and discharged as a by-product in the process of releasing natural gas from coal. Current practices of discharging large volumes of water into drainage channels or using it to irrigate cropland areas has the potential to elevate salinity and sodicity in soils. Elevated salinity affects the ability of plants to uptake water to facilitate biochemical processes such as photosynthesis and plant growth. Elevated sodicity in irrigation water adversely affects soil structure necessary for water infiltration, nutrient supply, and aeration. Salinity and sodicity concentrations are important in that a sodic soil can maintain its structure if the salinity level is maintained above the threshold electrolyte concentration. In this study, cropland soil and CBM water were treated with gypsum and sulfur. Changes in soil chemistry among different treatments were monitored using a split plot experiment. The CBM water used for irrigation had an EC of 1380 [mu]S cm−1 and SAR of 24.3 mmol12 L−12. Baseline and post treatment soil samples were collected to a depth of 60 cm within each study plot, analyzed, and characterized for chemical parameters. Comparisons between Spring 2004 and Fall 2004 soil chemistry data after one irrigation season (using the equivalent of 1 month of irrigation water or ≈12 inches) indicated that irrigating with Piney Creek water or a 50:50 blend of Piney Creek water and CBM water did not cause SAR values to increase. A combination of using a gypsum amendment to the soil along with a gypsum injection and sulfur burner treatment to the irrigation water resulted in the lowest SAR value in the first soil horizon among treatments irrigated solely with CBM produced water. The SAR value resulting from this combination treatment was 53% lower than using CBM water with no amendments to soil or water. Soil amendments to cores in the laboratory did not increase soil hydraulic conductivity when CBM water was applied.




Effects of the Surface Discharge of Coalbed Methane Produced Water on Water Quality and Macroinvertebrate Community of Structure in Headwater Streams of the Raton Basin, Colorado, USA


Book Description

Coalbed methane (CBM) is a type of natural gas produced from coal beds, and its extraction brings massive quantities of water from coal formations to the surface. CBM produced water is elevated in salinity and sodicity and can also contain heavy metals, trace elements, and organic compounds, all of which can be harmful to aquatic life. Discharge of produced water directly into streams is permitted in some CBM basins and has been occurring in the semi-arid Raton Basin of southern Colorado since the 1990s. Field studies assessing the impacts of this type of discharge on stream ecosystems have been few and have yielded equivocal results, and none have been conducted in the Raton Basin. The effects of the surface discharge of CBM produced water on the health of small headwater streams in a 30,000-acre State Wildlife Area in the Purgatoire River watershed of Las Animas County, Colorado were studied. Ten contaminated streams (below discharge points) and six comparable reference streams (having no discharge) were sampled and analyzed for differences in macroinvertebrate community structure and water quality. Non-metric multidimensional scaling ordinations showed significant separation in both water quality and community structure between the two stream types. Based on their concentrations and published regulatory/safe levels, the water quality parameters of concern in the produced water streams were determined to be: alkalinity, conductivity, chloride, pH, fluoride, aluminum, iron, temperature, dissolved oxygen, ammonia, and the sodium adsorption ratio (SAR). Reduced calcium and magnesium were also of concern. The biodiversity metrics Taxa Richness, EPT Richness, and Shannon-Wiener Diversity were all significantly lower in the produced water streams than the natural streams. Also, the Top 5 Taxa Percent was significantly higher, indicating lower diversity due to unevenness. The Colorado Macroinvertebrate Multimetric Index (MMI) did not differ between the two stream types, however. Stoneflies and oligochaetes were significantly reduced in both taxa richness and relative abundance in the produced water streams. Mayflies and caddisflies showed significantly decreased richness but unchanged relative abundance levels, due to certain tolerant taxa proliferating in the produced water streams. The variables showing the strongest correlation to biodiversity and community composition were calcium, SAR, and magnesium, with calcium appearing to have a protective effect on the communities. Though CBM produced water may not be as deleterious to aquatic life as other oil and gas produced waters, and although it is not regulated by EPA effluent guidelines, the present study shows that CBM produced water discharge can have significant and possibly long-lasting effects on small intermittent/ephemeral receiving streams.




Coalbed Methane Produced Water Management Guide - Treatment and Disposal to Surface Water: Black Warrior Basin, Alabama


Book Description

To assist coalbed methane operators in the Black Warrior Basin of Alabama in their efforts to manage produced waters in an environmentally acceptable manner by evaluating the performance of the produced water management systems currently in use and documenting these findings in a produced water management guide for treatment and discharge to surface waters.