Exhaust Particle Characterization for Lean and Stoichiometric DI Vehicles Operating on Ethanol-gasoline Blends


Book Description

Gasoline direct injection (GDI) engines can offer better fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet the U.S. fuel economy standards for 2016. Furthermore, lean-burn GDI engines can offer even higher fuel economy than stoichiometric GDI engines and have overcome challenges associated with cost-effective aftertreatment for NOx control. Along with changes in gasoline engine technology, fuel composition may increase in ethanol content beyond the current 10% due to the recent EPA waiver allowing 15% ethanol. In addition, the Renewable Fuels Standard passed as part of the 2007 Energy Independence and Security Act (EISA) mandates the use of biofuels in upcoming years. GDI engines are of environmental concern due to their high particulate matter (PM) emissions relative to port-fuel injected (PFI) gasoline vehicles; widespread market penetration of GDI vehicles may result in additional PM from mobile sources at a time when the diesel contribution is declining. In this study, we characterized particulate emissions from a European certified lean-burn GDI vehicle operating on ethanol-gasoline blends. Particle mass and particle number concentration emissions were measured for the Federal Test Procedure urban driving cycle (FTP 75) and the more aggressive US06 driving cycle. Particle number-size distributions and organic to elemental carbon ratios (OC/EC) were measured for 30 MPH and 80 MPH steady-state operation. In addition, particle number concentration was measured during wide open throttle accelerations (WOTs) and gradual accelerations representative of the FTP 75. Fuels included certification gasoline and 10% (E10) and 20% (E20) ethanol blends from the same supplier. The particle mass emissions were approximately 3 and 7 mg/mile for the FTP75 and US06, respectively, with lower emissions for the ethanol blends. The data are compared to a previous study on a U.S.-legal stoichiometric GDI vehicle operating on the same ethanol blends. The lean-burn GDI vehicle emitted a higher number of particles, but had an overall smaller average size. Particle number per mile decreased with increasing ethanol content for the transient tests. For the 30 and 80 mph tests, particle number concentration decreased with increasing ethanol content, although the shape of the particle size distribution remained the same. Engine-out OC/EC ratios were highest for the stoichiometric GDI vehicle with E20, but tailpipe OC/EC ratios were similar for all vehicles.




Nanoparticle Emissions From Combustion Engines


Book Description

This book focuses on particulate matter emissions produced by vehicles with combustion engines. It describes the physicochemical properties of the particulate matter, the mechanisms of its formation and its environmental impacts (including those on human beings). It discusses methods for measuring particulate mass and number, including the state-of-the-art in Portable Emission Measurement System (PEMS) equipment for measuring the exhaust emissions of both light and heavy-duty vehicles and buses under actual operating conditions. The book presents the authors’ latest investigations into the relations between particulate emission (mass and number) and engine operating parameters, as well as their new findings obtained through road tests performed on various types of vehicles, including those using diesel particulate filter regeneration. The book, which addresses the needs of academics and professionals alike, also discusses relevant European regulations on particulate emissions and highlights selected methods aimed at the reduction of particulate emissions from automobiles.




Physical Characterization of Exhaust Particle Emissions from Late Technology Gasoline Vehicles


Book Description

The study assesses the feasibility of introducing the regulated particle number measurement procedure for the regulation of gasoline vehicles, focusing on the established cut-off size of 23 nm. A range of late technology gasoline vehicles were tested under regulated and unregulated test conditions. The results indicated a distinct emission behavior of Direct Injection Gasolines (G-DI), Port Fuel Injection gasolines (PFI) and Diesels equipped with Particulate Filters (DPF), that differed both in terms of the absolute levels but also with respect to the fraction of undetected nano-sized non-volatile particles. The latter was found to be around 20% (based on comparisons with a Condensation Particle Counter (CPC) having a 50% cut-off size at 4.5 nm) for three G-DI vehicles tested, but ranged between 40 and 70% for the two PFIs measured. Interestingly, a relatively large fraction of undetected nanosized was also observed for two late technology DPFs, ranging between 30 and 50%.^To a large extent these differences originate from differences in the size distributions and the relatively blunt shape of the counting efficiency curve of PMP compliant CPCs. Under conditions favouring nucleation mode formation in the dilution tunnel, excessive particle concentrations were detected by the low cut-off size CPCs, and especially the one with a d50 at 4.5 nm, that could exceed those of the PMP compliant CPC by up to one order of magnitude. However, the concentration of these nano-sized particles was found to decrease with increasing the dilution ratio in the first stage of the Volatile Particle Remover (VPR), indicating that this is rather a volatile artifact possibly originating from re-nucleation of evaporated material downstream of the VPR. The study also investigated the potential offered by a range of available approaches to effectively control particle emissions from G-DIs.^These included the use of a Gasoline Particulate Filter (GPF), the introduction of ethanol in the fuel but also an advanced engine concept combining port and direct fuel injection. The GPF system was found to very efficient in controlling particle number emissions under all driving conditions, having no visible impact on carbon dioxide emissions. The use of fuel with hi-ethanol content (75-85%) was also found to be beneficial especially at high engine loads (up to 97% reduction of nonvolatile particle numbers) and during cold start operation (up to 70% reduction). The tests with the "hybrid" G-DI-PFI vehicle indicated that there exists the potential for significant reduction of PM formation through engine measures. The non-volatile particle number emissions of this vehicle remained below the diesel limit over all hot start tests.










Automobile Exhaust Emission Testing


Book Description

Differing legislation between the countries or unions of countries involved in pollution reduction has turned gas measuring technology into such an extremely extensive and complex field that only a few specialists in environmental agencies and the automobile industry have a grasp of it. This book is intended as an overview of the basics of exhaust gas measuring technology describing the interrelation between emissions, immissions and the effects of pollutants. It aims to provide experts and students alike with an understanding of the interrelationships and details within this field. The results presented are based on the experience gathered by the author during work spanning more than two decades in the automobile industry.