Metal–Molecular Assembly for Functional Materials


Book Description

This book focuses on modern coordination chemistry, covering porous coordination polymers, metalloproteins, metallopeptides, nanoclusters, nanocapsules, aligned polymers, and fullerenes. As well, it deals with applications to electronic devices and surface characterization. These wide-ranging topics are integrally described from the perspectives of dimensionality (one-, two-, and three-dimension), new materials design, synthesis, molecular assembly, function and application. The nine chapters making up this book have been authored by scientists who are at the cutting edge of research in this particular field. The level is appropriate for graduate students, post-doc researchers, and new faculty members whose aim is to become familiar with modern coordination chemistry from its basics to applications.







Supramolecular Nanotechnology


Book Description

Supramolecular Nanotechnology Provides up-to-date coverage of both current knowledge and new developments in the dynamic and interdisciplinary field of supramolecular nanotechnology In recent years, supramolecular nanotechnology has revolutionized research in chemistry, physics, and materials science. These easily manipulated molecular units enable the synthesis of novel nanomaterials for use in a wide range of current and potential applications including electronics, sensors, drug delivery, and imaging. Supramolecular Nanotechnology presents a state-of-the-art overview of functional self-assembling nanomaterials based on organic and polymeric molecules. Featuring contributions by an international panel of experts in the field, this comprehensive volume covers the design of self-assembled materials, their synthesis and diverse fabrication methods, the characterization of supramolecular architectures, and current and emerging applications in chemistry, biology, and medicine. Detailed chapters discuss the synthesis of peptide-based supramolecular structures and polymeric self-assembling materials, their characterization, advanced microscopy techniques, nanostructures made of porphyrins, polyelectrolytes, silica, their application in catalysis and cancer, atomistic and coarse-grained simulations, and more. Presents cutting-edge research on rationally designed, self-assembled supramolecular structures Discusses the impact of supramolecular nanotechnology on current and future research and technology Highlights applications of self-assembled supramolecular systems in catalysis, biomedical imaging, cancer therapies, and regenerative medicine Provides synthetic strategies for preparing the molecular assemblies and various characterization techniques for assessing the supramolecular morphology Describes theoretical modeling and simulation techniques for analyzing supramolecular nanostructures Supramolecular Nanotechnology: Advanced Design of Self-Assembled Functional Materials is essential reading for materials scientists and engineers, polymer and organic chemists, pharmaceutical scientists, molecular physicists and biologists, and chemical engineers.




Functional Metallosupramolecular Materials


Book Description

There is great interest in metallosupramolecular materials because of their use in magnetic, photonic and electronic materials. Functional Metallosupramolecular Materials focuses on the applications of these materials covering the chemistry underlying the synthesis of a variety of ligands to coordinate various metal ions and the generation of 2D and 3D materials based on these constructs. The book starts by looking at different metallosupramolecular systems including naturally occurring functional metallosupramolecular materials; DNA-based metallosupramolecular materials; metallopolymers; metallogels as well as functional materials based on MOFs. Subsequent chapters then systematically cover the different applications such as molecular computation, spin-crossover, light harvesting and as photocatalysts for the production of solar fuels. The book provides an overview of functional metallosupramolecular materials that will be of interest to graduate students, academics and industrial chemists interested in supramolecular chemistry, materials science and the materials applications. Priced at £159.00, US$260.00, €198.75




Molecular Self-Assembly


Book Description

In the past several decades, molecular self-assembly has emerged as one of the main themes in chemistry, biology, and materials science. This book compiles and details cutting-edge research in molecular assemblies ranging from self-organized peptide nanostructures and DNA-chromophore foldamers to supramolecular systems and metal-directed assemblies




Molecular Self-Assembly


Book Description

Self-assembly is undoubtedly a topic of special interest in current chemistry and is related to very wide scientific areas. Recent progress in this field seems to be featured by the construction of well-defined discrete systems exploiting complementary hydrogen bonding as well as coordination bonding. Seven leading international experts introduce the current topics in this very interesting field, focusing on two major subjects: organic assemblies and inorganic assemblies. All researchers who are interested in molecular recognition, material science, nanotechnology, and supramolecular chemistry will welcome this book as an inspiring source for creative research ideas.




Functional Materials from Colloidal Self-assembly


Book Description

A comprehensive resource for new and veteran researchers in the field of self-assembling and functional materials In Functional Materials from Colloidal Self-assembly, a pair of distinguished researchers delivers a thorough overview of how the colloidal self-assembly approach can enable the design and fabrication of several functional materials and devices. Among other topics, the book explores the foundations of self-assembly in different systems, nucleation, the growth of nanoparticles, self-assembly of colloidal microspheres for photonic crystals and devices, and the self-assembly of amphiphilic molecules as a template for mesoporous materials. The authors also discuss the self-assembly of biomolecules, superstructures from self-assembly, architectures from self-assembly, and the applications of self-assembled nanostructures. Functional Materials from Colloidal Self-assembly provides a balanced approach to the theoretical background and applications of the subject, offering sound guidance to both experienced and early-career researchers. The book also delivers: A thorough introduction to the fundamentals of colloids, including the theory of nucleation and the growth of colloidal particles Comprehensive explorations of mechanisms and strategies for the self-assembly of colloidal particles, including DNA-mediated colloidal self-assembly Practical discussions of characterization techniques for self-assembled colloidal structures, including electron microscopy techniques and X-ray techniques In-depth examinations of biological and biomedical materials, including tissue engineering, drug loading and release, and biodetection Perfect for materials scientists, inorganic chemists, and catalytic chemists, Functional Materials from Colloidal Self-assembly is also a must-read reference for biochemists and surface chemists seeking a one-stop resource on self-assembling and functional materials.




Materials Nanoarchitectonics


Book Description

Materials Nanoarchitectonics: From Integrated Molecular Systems to Advanced Devices provides the latest information on the design and molecular manipulation of self-organized hierarchically structured systems using tailor-made nanoscale materials as structural and functional units. The book is organized into three main sections that focus on molecular design of building blocks and hybrid materials, formation of nanostructures, and applications and devices. Bringing together emerging materials, synthetic aspects, nanostructure strategies, and applications, the book aims to support further progress, by offering different perspectives and a strong interdisciplinary approach to this rapidly growing area of innovation. This is an extremely valuable resource for researchers, advanced students, and scientists in industry, with an interest in nanoarchitectonics, nanostructures, and nanomaterials, or across the areas of nanotechnology, chemistry, surface science, polymer science, electrical engineering, physics, chemical engineering, and materials science. Offers a nanoarchitectonic perspective on emerging fields, such as metal-organic frameworks, porous polymer materials, or biomimetic nanostructures Discusses different approaches to utilizing "soft chemistry" as a source for hierarchically organized materials Offers an interdisciplinary approach to the design and construction of integrated chemical nano systems Discusses novel approaches towards the creation of complex multiscale architectures




Beyond the Molecular Frontier


Book Description

Chemistry and chemical engineering have changed significantly in the last decade. They have broadened their scopeâ€"into biology, nanotechnology, materials science, computation, and advanced methods of process systems engineering and controlâ€"so much that the programs in most chemistry and chemical engineering departments now barely resemble the classical notion of chemistry. Beyond the Molecular Frontier brings together research, discovery, and invention across the entire spectrum of the chemical sciencesâ€"from fundamental, molecular-level chemistry to large-scale chemical processing technology. This reflects the way the field has evolved, the synergy at universities between research and education in chemistry and chemical engineering, and the way chemists and chemical engineers work together in industry. The astonishing developments in science and engineering during the 20th century have made it possible to dream of new goals that might previously have been considered unthinkable. This book identifies the key opportunities and challenges for the chemical sciences, from basic research to societal needs and from terrorism defense to environmental protection, and it looks at the ways in which chemists and chemical engineers can work together to contribute to an improved future.




Hierarchical Assembly of Functional, Protein-Based Materials Via Coordination Chemistry and Computational Design


Book Description

Nature has long been a source of fascination, inspiration and humility for chemists. Despite our best efforts, the rate enhancements delivered by our catalysts fall orders of magnitude short of those achieved by enzymes, our drug delivery systems do not offer the selectivity and efficiency of viruses, and our materials do not have the ability to self-organize, self-repair and adapt to our changing needs the way that biological supramolecular polymers, such as the cytoskeleton does. A common theme in the above examples is nature's use of proteins to achieve these goals. Based on this premise, we set out to devise a method for hierarchically programming the self-assembly of a monomeric protein into functional materials. By using metal ions as the "molecular glue" that holds these complexes together, we have overcome many of the traditional issues in programming their assembly and shown that an unprecedented degree of chemical and thermal stability can be imparted on the protein subunits. Although we have not yet achieved the level of sophistication demonstrated by natural systems, our approach, which combines the fields of coordination chemistry, supramolecular chemistry, and computational design, has allowed us to assemble a single molecular precursor into a range of potentially useful structures.