Frontiers of 4D- and 5D-transition Metal Oxides


Book Description

This book is aimed at advanced undergraduates, graduate students and other researchers who possess an introductory background in materials physics and/or chemistry, and an interest in the physical and chemical properties of novel materials, especially transition metal oxides.New materials often exhibit novel phenomena of great fundamental and technological importance. Contributing authors review the structural, physical and chemical properties of notable 4d- and 5d-transition metal oxides discovered over the last 10 years. These materials exhibit extraordinary physical properties that differ significantly from those of the heavily studied 3d-transition metal oxides, mainly due to the relatively strong influence of the spin-orbit interaction and orbital order in 4d- and 5d materials. The immense growth in publications addressing the physical properties of these novel materials underlines the need to document recent advances and the current state of this field. This book includes overviews of the current experimental situation concerning these materials.




Physics of Spin-Orbit-Coupled Oxides


Book Description

This book is aimed at graduate students, post docs and senior researchers with preliminary expertise in materials physics or chemistry, and with an interest in the physical and chemical properties of 4d- and 5d transition metal oxides, especially ruthenates and iridates. The 4d- and 5d-transition metal oxides are among the most current and interesting quantum materials. This book reviews recent experimental and theoretical evidence that the physical and structural properties of these materials are decisively influenced by strong spin-orbit interactions that compete with comparable Coulomb, magnetic exchange and crystalline electric field interactions. This competition often leads to unusual ground states and magnetic frustration that are unique to this class of materials. Novel coupling between the orbital/lattice and spin degrees of freedom, which seriously challenge current theoretical models and are not addressed by traditional textbooks, are of particular interest, This book also reviews a few techniques for single-crystal growth that are most suitable for the 4d- and 5d-transition metal oxides. The discussion is intended to help fill an existing void in the literature describing relevant synthesis techniques for 4d- and 5d-materials, which is a daunting experimental challenge.










Pyrochlore Oxides


Book Description

This book presents an in-depth exploration of complex metal oxides, focusing on their applications in photocatalysis and biomedical materials. It highlights the practical importance of complex metal oxides, which have gained significant attention in recent years due to their diverse range of properties. The book specifically delves into the most representative series of compounds based on stable structural types of minerals, such as perovskite, fluorite, pyrochlore, corundum, and rutile. It also emphasizes the scientific interest in the pyrochlore mineral structure, which has been shown to exhibit photocatalytic activity. Recent studies have revealed that some compounds with the pyrochlore structure can act as promising candidates for photocatalysis. Additionally, the book highlights the use of photocatalysis in producing biomedical materials based on natural polymers. These materials possess a unique combination of components assembled in a specific structure, which makes them highly attractive for regenerative medicine associated with cell/tissue regeneration stimulation. Overall, this book offers a comprehensive analysis of the potential of complex metal oxides, particularly those with the pyrochlore structure, and is particularly useful for those researchers working in the fields of green chemistry and biomedical materials science.




Transition Metal Compounds


Book Description

This book describes all aspects of the physics of transition metal compounds, providing a comprehensive overview of this diverse class of solids. Set within a modern conceptual framework, this is an invaluable, up-to-date resource for graduate students, researchers and industrial practitioners in solid-state physics and chemistry, materials science, and inorganic chemistry.




Transition Metal Oxides


Book Description




Introduction to Frustrated Magnetism


Book Description

The field of highly frustrated magnetism has developed considerably and expanded over the last 15 years. Issuing from canonical geometric frustration of interactions, it now extends over other aspects with many degrees of freedom such as magneto-elastic couplings, orbital degrees of freedom, dilution effects, and electron doping. Its is thus shown here that the concept of frustration impacts on many other fields in physics than magnetism. This book represents a state-of-the-art review aimed at a broad audience with tutorial chapters and more topical ones, encompassing solid-state chemistry, experimental and theoretical physics.